15649-26-0

Upstream product

• 594-27-4 tetramethylstannane 
• 1124-19-2 phenyltin trichloride 
• 934-56-5 trimethyl(phenyl)stannane 
• 993-16-8 methyltin(IV) trichloride 
• 595-89-1 Tetraphenyllead 
• 1153-06-6 triphenyllead(IV) chloride 
• 1089-59-4 triphenyl methyl tin 

Downstream Products

• 57025-30-6 methylphenyltin dihydride 
• 17973-56-7 (α-C10H7)2Sn(CH3)(C6H5) 
• 78888-00-3 2-methyl-2-phenyl-1,3,6-trithia-2-stannocane 
• 78887-95-3 5-methyl-5-phenyl-1-oxa-4,6-dithia-5-stannocane 
• 116178-75-7 CH₃C₆H₅SnCl(SSP(OC₄H₉)2) 
• 116178-74-6 CH₃C₆H₅SnCl(SSP(O(CH₃)2CH)2) 
• 107019-90-9 [(C₆H₅)(CH₃)SnCl]2 
• 1066-45-1 trimethyltin(IV)chloride 
• 1080-43-9 dimethyldiphenyltin 
• 4167-84-4 diphenyl methyl tin chloride 
• 116178-63-3 (CH₃C₆H₅Sn(SSP(O(CH₃)2CH)2)2) 
• 116178-61-1 (CH₃C₆H₅Sn(SSP(OC₃H₇)2)2) 
• 116178-59-7 (CH₃C₆H₅Sn(SSP(OC₂H₅)2)2) 
• 75602-13-0 (C₆H₅)CH₃ClSnMn(CO)5 

Relevant academic research and scientific papers

Six-coordinate organotin(IV) complexes formed using the Kl?ui ligands; [CpCo{P(OR′)2O}3]SnR3 - nCln

The complexes [CpCo{P(OR′)2O}3]SnR3 - nCln [R′ = Me, Et; R = Ph, Me] are readily prepared from the corresponding organotin chloride and the sodium salt of the Kl?ui ligands. The X-ray crystal structures of the full series are reported for R = Ph, n = 0-3, and these show that they are all six-coordinate, including the Ph3Sn derivative which is the first example of a SnC3O3 coordination sphere. 1H, 13C, 31P and 119Sn NMR spectra are reported, and interpreted in terms of significant second-order effects and fluxional processes.

A utility for organoleads: Selective alkyl and aryl group transfer to tin

Me4Pb and Ph4Pb readily transfer methyl or phenyl groups to an equivalent molar ratio of tin(iv) chlorides in the order SnCl4 > MeSnCl3 > Me2SnCl2 > Me3SnCl, often in a selective manner. Me3PbCl and Ph3PbCl specifically transfer a single methyl/phenyl group under the same reaction conditions to produce recovered yields in >75%. Specific transfer of 2 methyl groups from PbMe4 can be achieved at elevated temperatures and/or a 2:1 molar ratio Pb:Sn.

ORIGINE DE L'ETAIN FORME DURANT LES ELECTROLYSES DU DICHLORURE DE METHYLPHENYLETAIN

Studies of electroreduction of methylphenyltin dichloride and dihydride enabled us to follow the formation of bis(chloromethylphenyltin).This dimer decays rapidly in the solid state.Migration of a phenyl group and disproportionation of the resulting chloromethyltin derivative initiated the formation of amalgamated tin and trisubstituted organotin compounds during electrolysis of the dichloride.

ORGANOMETALLIC COMPOUNDS. LXIX. SYNTHESIS AND PROPERTIES OF THE FIRST CHIRAL TRIORGANOSTANNYL-MANGANESE COMPLEX

Methyl-1-naphthylphenylstannyltetracarbonyl(diphenyl-N-methyl-N-(S)-1-phenylethylaminophosphine)manganese (I) has been prepared by two different routes from racemic methyl-1-naphthylphenyltin chloride.Fractional recrystallizations yielded two diastereomer