15649-26-0Relevant articles and documents
Six-coordinate organotin(IV) complexes formed using the Kl?ui ligands; [CpCo{P(OR′)2O}3]SnR3 - nCln
Lloyd, Nicholas C.,Nicholson, Brian K.,Wilkins, Alistair L.
, p. 2757 - 2766 (2006)
The complexes [CpCo{P(OR′)2O}3]SnR3 - nCln [R′ = Me, Et; R = Ph, Me] are readily prepared from the corresponding organotin chloride and the sodium salt of the Kl?ui ligands. The X-ray crystal structures of the full series are reported for R = Ph, n = 0-3, and these show that they are all six-coordinate, including the Ph3Sn derivative which is the first example of a SnC3O3 coordination sphere. 1H, 13C, 31P and 119Sn NMR spectra are reported, and interpreted in terms of significant second-order effects and fluxional processes.
ORIGINE DE L'ETAIN FORME DURANT LES ELECTROLYSES DU DICHLORURE DE METHYLPHENYLETAIN
Engel, Michele,Devaud, Marguerite
, p. 15 - 22 (2007/10/02)
Studies of electroreduction of methylphenyltin dichloride and dihydride enabled us to follow the formation of bis(chloromethylphenyltin).This dimer decays rapidly in the solid state.Migration of a phenyl group and disproportionation of the resulting chloromethyltin derivative initiated the formation of amalgamated tin and trisubstituted organotin compounds during electrolysis of the dichloride.
