dichloro(methyl)phenylstannane

Base Information

Chemical Name:dichloro(methyl)phenylstannane
CAS No.:15649-26-0
Molecular Formula:C7H8 Cl2 Sn
Molecular Weight:281.757
Hs Code.:
Mol file:15649-26-0.mol

Synonyms:Dichloromethylphenylstannane;Dichloromethylphenyltin; Methyl(phenyl)tin dichloride; Methylphenylstannyldichloride; NSC 319706

Suppliers and Price of dichloro(methyl)phenylstannane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of dichloro(methyl)phenylstannane

Chemical Property:

Vapor Pressure:0.101mmHg at 25°C
Boiling Point:230.1°Cat760mmHg
Flash Point:93°C
Density:g/cm³

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of dichloro(methyl)phenylstannane

There total 7 articles about dichloro(methyl)phenylstannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 594-27-4
tetramethylstannane

: 1124-19-2
phenyltin trichloride

: 1066-45-1
trimethyltin(IV)chloride

: 15649-26-0
methylphenyltin(IV) dichloride

Guidance literature:: equimolar amts. of educts, 0°C, 1.5h;
DOI:10.1021/jo01267a042

Reference yield: 97.0%

: 594-27-4
tetramethylstannane

: 1124-19-2
phenyltin trichloride

: 15649-26-0
methylphenyltin(IV) dichloride

Guidance literature:: In neat (no solvent); byproducts: (CH3)3SnCl; (N2); cooling of PhSnCl3 in Schlenk flask to 0°C; addn. dropwise of SnMe4 with stirring; stirring for 0.5 h ((J. Org. Chem. 33 (1968) 1119); pumping under vac. at room temp. for several hs; GS-MS;
DOI:10.1016/j.jorganchem.2006.02.010

Reference yield: 96.0%

: 1089-59-4
triphenyl methyl tin

: 15649-26-0
methylphenyltin(IV) dichloride

Guidance literature:: With hydrogenchloride; In diethyl ether; 0.93 N HCl/Et2O added dropwise at 0°C during 2 h to Ph3SnMe in dry Et2O, reaction was complete after 48 h; evapn. of solvent, residue crystd. in refrigerator, purified by sublimation; elem. anal.;
DOI:10.1016/S0022-328X(00)85782-4