1,1,2,2-tetramesityl-1-chloro-2-(dichloromethyl)digermane

Base Information

• Chemical Name: 1,1,2,2-tetramesityl-1-chloro-2-(dichloromethyl)digermane
• CAS No.: 328001-35-0
• Molecular Formula: C₃₇H₄₅Cl₃Ge₂
• Molecular Weight: 741.303
• Mol file: 328001-35-0.mol

Synonyms:

Chemical Property of 1,1,2,2-tetramesityl-1-chloro-2-(dichloromethyl)digermane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,1,2,2-tetramesityl-1-chloro-2-(dichloromethyl)digermane

There total 2 articles about 1,1,2,2-tetramesityl-1-chloro-2-(dichloromethyl)digermane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 25.0%

triethylsilane (617-86-7) + hexamesitylcyclotrigermane (107824-84-0) + chloroform (67-66-3,8013-54-5) → dimesityl(triethylsilyl)germane (144435-57-4) + 1,1,2,2-tetramesityl-1-chloro-2-(dichloromethyl)digermane (328001-35-0)

Guidance literature:

In toluene; Irradiation (UV/VIS); Ge-complex and Et3SiH were dissolved in toluene, photolyzed at -70°C for 16 h, CHCl3 was added under Ar; solvent was removed in vacuo, TLC on silica gel with CH2Cl2/hexane;

DOI:10.1021/om0008530

Reference yield: 25.0%

tetrakis(2,4,6-trimethylphenyl)digermene (115385-07-4) + chloroform (67-66-3,8013-54-5) → 1,1,2,2-tetramesityl-1-chloro-2-(dichloromethyl)digermane (328001-35-0)

Guidance literature:

In toluene; -40°C;

DOI:10.1139/V10-082

upstream raw materials:

triethylsilane

hexamesitylcyclotrigermane

chloroform

tetrakis(2,4,6-trimethylphenyl)digermene