triphenylbismuth(V) dipropionate

Base Information

Chemical Name:triphenylbismuth(V) dipropionate
CAS No.:61174-97-8
Molecular Formula:C₂₄H₂₅BiO₄
Molecular Weight:586.441
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of triphenylbismuth(V) dipropionate

Chemical Property:

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Technology Process of triphenylbismuth(V) dipropionate

There total 4 articles about triphenylbismuth(V) dipropionate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 603-33-8
triphenylbismuthane

: 802294-64-0,79-09-4
propionic acid

: 61174-97-8,153380-10-0
triphenylbismuth(V) dipropionate

Guidance literature:: With tert.-butylhydroperoxide; In diethyl ether; byproducts: t-BuOH, H2O; t-BuOOH (5 mmol) was added dropwise to a stirred cold (5-10°C) soln. of Ph3Bi (5 mmol) and carboxylic acid (10 mmol) in Et2O; the mixt. was kept in the dark for 24 h at room temp.; the solvent was distd. off under reduced pressure; purifn. by recrystn. (CHCl3/hexane);
DOI:10.1016/j.jorganchem.2005.04.051

Reference yield: 15.0%

: 603-33-8
triphenylbismuthane

: 153289-73-7
triphenylbismuth diformate

: 28899-97-0,7239-60-3
triphenylbismuth(V) diacetate

: 61174-97-8,153380-10-0
triphenylbismuth(V) dipropionate

Guidance literature:: With ozone; butan-2-one; In butanone; BiPh3 soln. added at -78°C to ozone-satd. butane-2-one; suspn. warmed to ambient temp. while being flushed with Ar; react. mechanism discussed; suspn. filtered through Celite; filtrate evapd. in vac. to give mixt. of BiPh3 (14%), the diformate, the diacetate, and the dipropionate; yields estd. 1H NMR spect.;

Reference yield: 4.0%

: 603-33-8
triphenylbismuthane

: 153289-73-7
triphenylbismuth diformate

: 61174-97-8,153380-10-0
triphenylbismuth(V) dipropionate

Guidance literature:: With ozone; ethylbenzene; In ethylbenzene; byproducts: acetophenone, 1-phenylethanol; ozonized oxygen passed into ethylbenzene at -78°C for 1 h; soln. warmed to ambient temp. while being flushed with Ar; Ph3Bi added; mixt. stirred for 1 h; react. mechanism discussed; removal of solvent in vac. left a mixture of the diformate, the dipropionate, acetophenone (<1%), and 1-phenylethanol (<1%) as estd. by 1H NMR spectroscopy; the dipropionate isolated; elem. anal.;