[(2,6-(Ph2PO)2C6H3-κ3C,P,P')Ni(CN)]

Base Information

• Chemical Name: [(2,6-(Ph2PO)2C6H3-κ3C,P,P')Ni(CN)]
• CAS No.: 1330059-33-0
• Molecular Formula: C₃₁H₂₃NNiO₂P₂
• Molecular Weight: 562.167
• Mol file: 1330059-33-0.mol

Synonyms:

Chemical Property of [(2,6-(Ph2PO)2C6H3-κ3C,P,P')Ni(CN)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(2,6-(Ph2PO)2C6H3-κ3C,P,P')Ni(CN)]

There total 3 articles about [(2,6-(Ph2PO)2C6H3-κ3C,P,P')Ni(CN)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

silver cyanide (330660-35-0) + [(2,6-(Ph2PO)2C6H3-κ3C,P,P')NiBr] (1303996-71-5) → [(2,6-(Ph2PO)2C6H3-κ3C,P,P')Ni(CN)] (1330059-33-0)

Guidance literature:

In dichloromethane; (N2); addn. of AgCN to soln. of nickel compd. in CH2Cl2, stirring at room temp. for 5 h in dark; evapn., extn., filtration through silica gel, evapn. in vac., elem. anal.;

DOI:10.1039/c1dt10381d

Reference yield: 63.0%

potassium cyanide + [(2,6-(Ph2PO)2C6H3-κ3C,P,P')NiBr] (1303996-71-5) → [(2,6-(Ph2PO)2C6H3-κ3C,P,P')Ni(CN)] (1330059-33-0)

Guidance literature:

In tetrahydrofuran; (N2); addn. of KCN to soln. of nickel compd. in THF, stirring at 60°C for 24 h; evapn., extn., filtration through silica gel, evapn. in vac., elem. anal.;

DOI:10.1039/c1dt10381d

Reference yield:

1,3-bis(diphenylphosphinito)benzene (279214-81-2) → [(2,6-(Ph2PO)2C6H3-κ3C,P,P')Ni(CN)] (1330059-33-0)

Guidance literature:

Multi-step reaction with 2 steps

1: toluene

2: dichloromethane

In dichloromethane; toluene;

DOI:10.1039/c1dt10381d

upstream raw materials:

1,3-bis(diphenylphosphinito)benzene

silver cyanide

[(2,6-(Ph2PO)2C6H3-κ3C,P,P')NiBr]