bis(cyclopentadienyl)methyltitanium(IV) tetrakis(pentafluorophenyl)borate

Base Information

• Chemical Name: bis(cyclopentadienyl)methyltitanium(IV) tetrakis(pentafluorophenyl)borate
• CAS No.: 625855-35-8
• Molecular Formula: C₁₁H₁₃Ti*C₂₄BF₂₀
• Molecular Weight: 872.147
• Mol file: 625855-35-8.mol

Synonyms:

Chemical Property of bis(cyclopentadienyl)methyltitanium(IV) tetrakis(pentafluorophenyl)borate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis(cyclopentadienyl)methyltitanium(IV) tetrakis(pentafluorophenyl)borate

There total 5 articles about bis(cyclopentadienyl)methyltitanium(IV) tetrakis(pentafluorophenyl)borate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dimethyltitanocene (1271-66-5) + trityl tetrakis(pentafluorophenyl)borate → bis(cyclopentadienyl)methyltitanium(IV) tetrakis(pentafluorophenyl)borate (625855-35-8)

Guidance literature:

In further solvent(s); byproducts: (C6H5)3CCH3; (N2 or Ar); using Schlenk techniques; dissolving of TiCp2Me2 and (Ph3C)(B(C6F5)4) in C6D5Br for 10 min; monitoring by NMR;

DOI:10.1021/om060096r

Reference yield:

dimethyltitanocene (1271-66-5) + 1,2,3-triphenylcyclopropenium tetrakis(pentafluorophenyl)borate → bis(cyclopentadienyl)methyltitanium(IV) tetrakis(pentafluorophenyl)borate (625855-35-8)

Guidance literature:

In dichloromethane; stoichiometric amounts, room temp.; not sepd., detected by NMR spectra;

DOI:10.1139/v03-047

Reference yield:

dimethyltitanocene (1271-66-5) + dichloromethane-d2 (1665-00-5) + water (7732-18-5) + trityl tetrakis(pentafluorophenyl)borate → bis(cyclopentadienyl)methyltitanium(IV) tetrakis(pentafluorophenyl)borate (625855-35-8) + [Cp2TiMe(water)][B(C6F5)4] (1253852-11-7)

Guidance literature:

In dichloromethane-d2; byproducts: CH3C(C6H5)3; (Ar); dissolving titanium compd. in CD2Cl2 soln. of trityl salt at 293 K, cooling to 195 K, addn. of soln. of water in CD2Cl2; NMR monitoring at 205 K;

DOI:10.1021/om100660w

upstream raw materials:

dimethyltitanocene

dichloromethane-d2

water

water-d2

Downstream raw materials:

(C(CH₃)3)3PCO₂Ti(C₅H₅)2Cl⁽¹⁺⁾*B(C₆F₅)4^(1-)=(C₄H₉)3PCO₂Ti(C₅H₅)2ClB(C₆F₅)4