2-(6-Methoxynaphthalen-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Base Information

Chemical Name:2-(6-Methoxynaphthalen-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
CAS No.:269410-13-1
Molecular Formula:C₁₇H₂₁BO₃
Molecular Weight:284.163
Hs Code.:
DSSTox Substance ID:DTXSID501160771
Nikkaji Number:J3.246.783K
Mol file:269410-13-1.mol

Synonyms:269410-13-1;2-(6-methoxynaphthalen-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;2-(6-methoxy-2-naphthyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;1,3,2-Dioxaborolane, 2-(6-methoxy-2-naphthalenyl)-4,4,5,5-tetramethyl-;starbld0027772;2-(6-methoxy-2-naphthalenyl)-4,4,5,5-tetramethyl-1,3,2-Dioxaborolane;AQ-747/41761876;SCHEMBL2508208;DTXSID501160771;AKOS018222623;CS-0356733;FT-0725816;EN300-3249816;2-(6-methoxy-naphthalen-2-yl)-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane;2-(6-methoxynaphthalen-2-yl)-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane

Suppliers and Price of 2-(6-Methoxynaphthalen-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 6 raw suppliers

Chemical Property of 2-(6-Methoxynaphthalen-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Chemical Property:

Boiling Point:413.8±18.0 °C(Predicted)
Density:1.08±0.1 g/cm3(Predicted)
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:2
Exact Mass:284.1583747
Heavy Atom Count:21
Complexity:366

Purity/Quality:: 99%,98%, ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:B1(OC(C(O1)(C)C)(C)C)C2=CC3=C(C=C2)C=C(C=C3)OC

Technology Process of 2-(6-Methoxynaphthalen-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

There total 15 articles about 2-(6-Methoxynaphthalen-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 5111-65-9
2-Bromo-6-methoxynaphthalene

: 73183-34-3
bis(pinacol)diborane

: 269410-13-1
2-(6-methoxy-naphthalen-2-yl)-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane

Guidance literature:: With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂; potassium acetate; In 1,2-dichloro-ethane; at 80 ℃; for 18h;
DOI:10.1021/acs.joc.9b01844

Reference yield: 95.0%

: 76-09-5
2,3-dimethyl-2,3-butane diol

: 156641-98-4
(6-methoxy-2-naphthalene)boronic acid

: 269410-13-1
2-(6-methoxy-naphthalen-2-yl)-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane

Guidance literature:: In tetrahydrofuran; at 20 ℃; for 12h; Molecular sieve;
DOI:10.1039/c8cc09523j

Reference yield: 83.0%

: 55090-57-8
phenyl 6-methoxy-2-naphthoate

: 73183-34-3
bis(pinacol)diborane

: 269410-13-1
2-(6-methoxy-naphthalen-2-yl)-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane

Guidance literature:: With bis(1,5-cyclooctadiene)nickel ⁽⁰⁾; tributylphosphine; lithium carbonate; In 1,4-dioxane; at 160 ℃; for 36h; Glovebox; Sealed tube;
DOI:10.1002/chem.201604504