NacNacFe-Et

Base Information

• Chemical Name: NacNacFe-Et
• CAS No.: 506406-67-3
• Molecular Formula: C₃₁H₄₆FeN₂
• Molecular Weight: 502.567
• Mol file: 506406-67-3.mol

Synonyms:

Chemical Property of NacNacFe-Et

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of NacNacFe-Et

There total 5 articles about NacNacFe-Et which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

ethene (74-85-1) + (2,4-bis(2,6-diisopropylphenylimino)pent-3-yl)Fe(isobutyl) (506406-65-1) → NacNacFe-Et (506406-67-3)

Guidance literature:

heated at 60°C; elem. anal.;

DOI:10.1039/b209389h

Reference yield: 72.0%

triethyl borane (97-94-9) + [(2,4-bis(2,6-diisopropylphenylimino)pent-3-yl)Fe(μ-H)]2 (854669-50-4) → NacNacFe-Et (506406-67-3) + (2,4-bis(2,6-diisopropylphenylimino)pent-3-yl)Fe(μ-H)2BEt2 (944160-02-5)

Guidance literature:

In hexane; toluene; under N2; Fe complex dissolved in toluene; BEt3 in hexane added; heated at 70°C for 14 h; volatiles removed under vac.; extd. with pentane; filtered; concd.; crystd. from pentane at -35°C (Fe-B complex); elem. anal.;

DOI:10.1021/om7003805

Reference yield:

(CH3)2C3HN2[[(CH3)2CH]2C6H3]2Fe(1+)*Cl2Li(C4H8O)2(1-)=[(CH3)2C3HN2[[(CH3)2CH]2C6H3]2Fe][Cl2Li(C4H8O)2] (374566-93-5) → NacNacFe-Et (506406-67-3)

Guidance literature:

Multi-step reaction with 2 steps

1: diethyl ether

In diethyl ether;

DOI:10.1039/b209389h

upstream raw materials:

ethene

(2,4-bis(2,6-diisopropylphenylimino)pent-3-yl)Fe(isobutyl)

(CH₃)2C₃HN₂[[(CH₃)2CH]2C₆H₃]2Fe⁽¹⁺⁾*Cl₂Li(C₄H₈O)2^(1-)=[(CH₃)2C₃HN₂[[(CH₃)2CH]2C₆H₃]2Fe][Cl₂Li(C₄H₈O)2]

ethylmagnesium chloride