[Ni(2,6,12,16,21,22-hexaaza-3,5,13,15-tetraphenyltricyclo[15,3,1,1(7-11)]docosa-1⁽²¹⁾,2,5,7,9,11⁽²²⁾,12,15,17,19-decaene)Cl₂]

Base Information

• Chemical Name: [Ni(2,6,12,16,21,22-hexaaza-3,5,13,15-tetraphenyltricyclo[15,3,1,1(7-11)]docosa-1⁽²¹⁾,2,5,7,9,11⁽²²⁾,12,15,17,19-decaene)Cl₂]
• CAS No.: 187386-14-7
• Molecular Formula: C₄₀H₃₀Cl₂N₆Ni
• Molecular Weight: 724.314
• Mol file: 187386-14-7.mol

Synonyms:

Chemical Property of [Ni(2,6,12,16,21,22-hexaaza-3,5,13,15-tetraphenyltricyclo[15,3,1,1(7-11)]docosa-1⁽²¹⁾,2,5,7,9,11⁽²²⁾,12,15,17,19-decaene)Cl₂]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ni(2,6,12,16,21,22-hexaaza-3,5,13,15-tetraphenyltricyclo[15,3,1,1(7-11)]docosa-1⁽²¹⁾,2,5,7,9,11⁽²²⁾,12,15,17,19-decaene)Cl₂]

There total 2 articles about [Ni(2,6,12,16,21,22-hexaaza-3,5,13,15-tetraphenyltricyclo[15,3,1,1(7-11)]docosa-1⁽²¹⁾,2,5,7,9,11⁽²²⁾,12,15,17,19-decaene)Cl₂] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

2,6,12,16,21,22-hexaaza-3,5,13,15-tetraphenyltricyclo[15,3,1,1(7-11)]docosa-1(21),2,5,7,9,11(22),12,15,17,19-decaene + nickel dichloride (83864-14-6) → [Ni(2,6,12,16,21,22-hexaaza-3,5,13,15-tetraphenyltricyclo[15,3,1,1(7-11)]docosa-1(21),2,5,7,9,11(22),12,15,17,19-decaene)Cl2] (123321-77-7,187386-14-7)

Guidance literature:

In ethanol; hot solns. of ligand and Ni salt in EtOH mixed with stirring, mixt. refluxed; cooled, solid filtered off, washed with cold EtOH, dried over P4O10 under vac.; elem. anal.;

DOI:10.1016/j.saa.2007.08.027

Reference yield:

2.6-diaminopyridine (141-86-6) + 1,3-diphenylpropanedione (120-46-7,61346-73-4) + nickel dichloride (83864-14-6) → Ni(C40H30N6)Cl2 (123321-77-7,187386-14-7)

Guidance literature:

With hydrogenchloride; In methanol; reflux (water-bath), HCl addn., reflux (24 h), soln. concn., standing (2d), crystn.; washing (methanol, ether), drying (red. pressure); elem. anal.;

Reference yield:

Ni(C40H30N6)Cl2 (123321-77-7,187386-14-7) + sodium bromide (7647-15-6) → Ni(C40H30N6)Br2 (123321-78-8,187386-15-8)

Guidance literature:

With nickel dichloride; In ethanol; byproducts: NaCl; stirring, NaCl filtration; elem. anal.;

upstream raw materials:

nickel dichloride

2.6-diaminopyridine

1,3-diphenylpropanedione

Downstream raw materials:

Ni(C₄₀H₃₀N₆)Br₂

Ni(C₄₀H₃₀N₆)(NCS)2