{(tris(2-pyridylmethyl)amine)(acetonitrile)copper(I)} perchlorate

Base Information

Chemical Name:{(tris(2-pyridylmethyl)amine)(acetonitrile)copper(I)} perchlorate
CAS No.:147186-13-8
Molecular Formula:C₂₀H₂₁CuN₅*ClO₄
Molecular Weight:494.417
Hs Code.:

Synonyms:

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Chemical Property of {(tris(2-pyridylmethyl)amine)(acetonitrile)copper(I)} perchlorate

Chemical Property:

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Technology Process of {(tris(2-pyridylmethyl)amine)(acetonitrile)copper(I)} perchlorate

There total 1 articles about {(tris(2-pyridylmethyl)amine)(acetonitrile)copper(I)} perchlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: [(tetrakis(2,6-difluorophenyl)porphyrinato)Fe(III)(μ-η2:η1-peroxo)Cu(II)(tris(2-pyridylmethyl)amine)](1+)

: 1493-13-6
trifluorormethanesulfonic acid

: 75-05-8,26809-02-9
acetonitrile

: 285141-34-6
[Cu(II)(tris(2-pyridylmethyl)amine)(CN)]⁽¹⁺⁾

: 944911-14-2
[Cu(II)(tris(2-pyridylmethyl)amine)(CF₃SO₃)]⁽¹⁺⁾

: 288394-53-6
[Fe(III)(tetrakis(2,6-difluorophenyl)porphyrinate)(CF₃SO₃)]

: 147186-13-8
{(tris(2-pyridylmethyl)amine)(acetonitrile)copper(I)} perchlorate

Guidance literature:: In acetonitrile; na excess of acid was added to a soln. of complex in CH3CN at -40°C; detected by spectra;
DOI:10.1021/ic700363k

Reference yield: 78.9%

: 147186-13-8
{(tris(2-pyridylmethyl)amine)(acetonitrile)copper(I)} perchlorate

: 60-29-7,927820-24-4
diethyl ether

: 79060-88-1
sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate

: Cu(tris(2-pyridylmethyl)amine)(tetrakis(3,5-bis(trifluoromethylphenyl))borate)*Et₂O

Guidance literature:: In diethyl ether; Na-salt in Et2O was added to Cu-complex under Ar, stirred for 1 h at room temp.; filtered, volatiles were removed under vac.; elem. anal.;
DOI:10.1021/ic0205684

Reference yield: 70.0%

: 1122-58-3
dmap

: 147186-13-8
{(tris(2-pyridylmethyl)amine)(acetonitrile)copper(I)} perchlorate

: tetrakis(2,6-difluorophenyl)porphyrinatoiron(II) hydrate

: (4-dimethylaminopyridine)tetrakis(2,6-difluorophenyl)porphyrinatoiron(II) monohydrate

Guidance literature:: In acetonitrile; byproducts: O2; (N2); dissolving 1:1 mixt. of iron compd. and copper compd. in CH3CN, bubbling O2 at -40°C, addn. of CH3CN soln. of pyridine deriv. at -40°C; filtration under Ar, washing, drying in vac. for 2 h, elem. anal.;
DOI:10.1021/ic9020993