[(2,2'-bipyridine)2Ru(κ-C,N-2-(dimesitylborylphenyl)pyridinato)]OTf

Base Information

• Chemical Name: [(2,2'-bipyridine)2Ru(κ-C,N-2-(dimesitylborylphenyl)pyridinato)]OTf
• CAS No.: 1203511-87-8
• Molecular Formula: CF₃O₃S*C₄₉H₄₅BN₅Ru
• Molecular Weight: 964.881
• Mol file: 1203511-87-8.mol

Synonyms:

Chemical Property of [(2,2'-bipyridine)2Ru(κ-C,N-2-(dimesitylborylphenyl)pyridinato)]OTf

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(2,2'-bipyridine)2Ru(κ-C,N-2-(dimesitylborylphenyl)pyridinato)]OTf

There total 1 articles about [(2,2'-bipyridine)2Ru(κ-C,N-2-(dimesitylborylphenyl)pyridinato)]OTf which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

cis-dichlorobis(2,2′-bipyridine)ruthenium(II) (345911-20-8,19542-80-4,158060-65-2,34795-02-3,15746-57-3) + 2-(4-(dimesitylboryl)phenyl)pyridine (790299-75-1) + silver trifluoromethanesulfonate (2923-28-6) → [(2,2'-bipyridine)2Ru(κ-C,N-2-(dimesitylborylphenyl)pyridinato)]OTf (1203511-87-8)

Guidance literature:

In methanol; dichloromethane; (N2); std. Schlenk technique; Ag salt was added to soln. of Ru complex and ligand in CH2Cl2/MeOH; refluxed for 2 h; evapd. (vac.); extd. (CH2Cl2); filtered over Celite; solvent removed; washed (Et2O, cold MeCN); recrystd. by slow diffusion Et2O into CH2Cl2 soln.; elem. anal.;

DOI:10.1021/ic9020349

Reference yield:

[(2,2'-bipyridine)2Ru(κ-C,N-2-(dimesitylborylphenyl)pyridinato)]OTf (1203511-87-8) + tetraethylammoniumcyanide (13435-20-6) → [(2,2'-bipyridine)2Ru(NC5H4C6H2B(mesityl)2CN)] (1203511-89-0)

Guidance literature:

In perdeuteriopyridine; (N2); std. Schlenk technique; cyanide was added to soln. of Ru complex in pyridine-d5; NMR monitoring;

DOI:10.1021/ic9020349

Reference yield:

[(2,2'-bipyridine)2Ru(κ-C,N-2-(dimesitylborylphenyl)pyridinato)]OTf (1203511-87-8) + tetrabutyl ammonium fluoride (429-41-4) → [(2,2'-bipyridine)2Ru(NC5H4C6H2B(mesityl)2F)] (1203511-88-9)

Guidance literature:

In perdeuteriopyridine; (N2); std. Schlenk technique; fluoride was added to soln. of Ru complex in pyridine-d5; NMR monitoring;

DOI:10.1021/ic9020349

upstream raw materials:

cis-dichlorobis(2,2′-bipyridine)ruthenium(II)

2-(4-(dimesitylboryl)phenyl)pyridine

silver trifluoromethanesulfonate

Downstream raw materials:

[(2,2'-bipyridine)2Ru(NC₅H₄C₆H₂B(mesityl)2CN)]

[(2,2'-bipyridine)2Ru(NC₅H₄C₆H₂B(mesityl)2CN)]*CH₃OH

[(2,2'-bipyridine)2Ru(NC₅H₄C₆H₂B(mesityl)2F)]