(C₁₀H₆P(C₆H₅)2)2PdC₆H₅Br

Base Information

• Chemical Name: (C₁₀H₆P(C₆H₅)2)2PdC₆H₅Br
• CAS No.: 1005420-28-9
• Molecular Formula: C₅₀H₃₇BrP₂Pd
• Molecular Weight: 886.115
• Mol file: 1005420-28-9.mol

Synonyms:

Chemical Property of (C₁₀H₆P(C₆H₅)2)2PdC₆H₅Br

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (C₁₀H₆P(C₆H₅)2)2PdC₆H₅Br

There total 1 articles about (C₁₀H₆P(C₆H₅)2)2PdC₆H₅Br which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bromobenzene (108-86-1,52753-63-6) + [palladium(S-BINAP)2] → (C10H6P(C6H5)2)2PdC6H5Br (275801-25-7,1005420-28-9)

Guidance literature:

In not given; (inert atm.); reaction at 45°C; Kinetics;

DOI:10.1021/om0108088

Reference yield: 87.1%

1-amino-3-methylbutane (107-85-7) + (C10H6P(C6H5)2)2PdC6H5Br (275801-25-7,1005420-28-9) + silver trifluoromethanesulfonate (2923-28-6) → (C10H6P(C6H5)2)2PdC6H5NH2(CH2)2CH(CH3)2(1+)*OSO2CF3(1-)*0.5C6H5CH3=[(C10H6P(C6H5)2)2PdC6H5NH2C2H4C3H7]OSO2CF3*0.5C6H5CH3

Guidance literature:

In dichloromethane; (inert atm.); addn. of amine to a soln. of palladium complex in CH2Cl2, addn. of silver salt, stirring at room temp. for 5 min; decantation, filtration, extn. with CH2Cl2, filtration through Celite, concn., layering with toluene, keeping at -34°C for 1 h, layering with heptane, keeping at -34°C overnight, recrystn. (toluene), filtration; elem. anal.;

DOI:10.1021/om0108088

Reference yield: 87.1%

n-Octylamine (111-86-4) + (C10H6P(C6H5)2)2PdC6H5Br (275801-25-7,1005420-28-9) + silver trifluoromethanesulfonate (2923-28-6) → [(C10H6P(C6H5)2)2PdC6H5NH2(CH2)7CH3](1+)*OSO2CF3(1-)=[(C10H6P(C6H5)2)2PdC6H5NH2(CH2)7CH3]OSO2CF3 (403619-20-5)

Guidance literature:

In toluene; (inert atm.); addn. of amine to a suspn. of palladium complex in toluene, addn. of silver salt, stirring at room temp. for 5 min; decantation, filtration, extn. with toluene, filtration through Celite, concn., layering with pentane, keeping at -34°C overnight, filtration; elem. anal.;

DOI:10.1021/om0108088

upstream raw materials:

bromobenzene

Downstream raw materials:

[Pd(BINAP)(I)(Ph)]

[(C₁₀H₆P(C₆H₅)2)2PdC₆H₅NH₂(CH₂)7CH₃]⁽¹⁺⁾*OSO₂CF₃^(1-)=[(C₁₀H₆P(C₆H₅)2)2PdC₆H₅NH₂(CH₂)7CH₃]OSO₂CF₃

(C₁₀H₆P(C₆H₅)2)2PdC₆H₅Cl