1'-Methylmurrangatin

Base Information

• Chemical Name: 1'-Methylmurrangatin
• CAS No.: 109273-96-3
• Molecular Formula: C₁₆H₁₈O₅
• Molecular Weight: 290.316
• Mol file: 109273-96-3.mol

Synonyms:

Chemical Property of 1'-Methylmurrangatin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1'-Methylmurrangatin

There total 3 articles about 1'-Methylmurrangatin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

methanol (67-56-1) + Phebalosin (6545-99-9) → 8-(1,2-dihydroxy-3-methylbut-3-enyl)-7-methoxychromen-2-one (56946-30-6) + 7-methoxy-8-(1'-methoxy-2'-hydroxy-3'-methyl-Δ3'-butenyl)coumarin (109273-96-3,6432-67-3,147731-94-0,147731-95-1,120786-75-6,120786-76-7) + murralongin (53011-72-6)

Guidance literature:

With sulfuric acid; In water; at 60 ℃; for 5h;

DOI:10.1248/cpb.34.3978

Reference yield: 40.0%

Phebalosin (6545-99-9) → minumicrolin (37126-91-3,56946-30-6,88546-96-7,106975-21-7,121960-62-1,121960-64-3,124988-29-0) + 1'-Methylmurrangatin (6432-67-3,109273-96-3,120786-75-6,120786-76-7,147731-94-0,147731-95-1)

Guidance literature:

With oxalic acid; In methanol; for 3h; Heating;

Reference yield: 30.0%

methanol (67-56-1) + Phebalosin (6545-99-9) → minumicrolin (37126-91-3,56946-30-6,88546-96-7,106975-21-7,121960-62-1,121960-64-3,124988-29-0) + 1'-Methylmurrangatin (6432-67-3,109273-96-3,120786-75-6,120786-76-7,147731-94-0,147731-95-1)

Guidance literature:

With oxalic acid; for 3h; Heating;

upstream raw materials:

methanol

Phebalosin