Fe(SPh)(CO)(PMe3)(η-C5H5)

Base Information

Chemical Name:Fe(SPh)(CO)(PMe3)(η-C5H5)
CAS No.:76452-71-6
Molecular Formula:C₁₅H₁₉FeOPS
Molecular Weight:334.202
Hs Code.:

Synonyms:

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Chemical Property of Fe(SPh)(CO)(PMe3)(η-C5H5)

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Technology Process of Fe(SPh)(CO)(PMe3)(η-C5H5)

There total 1 articles about Fe(SPh)(CO)(PMe3)(η-C5H5) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 12110-44-0
CpFe(CO)3SC6H5

: 594-09-2
trimethylphosphane

: 76452-71-6
Fe(SPh)(CO)(PMe3)(η-C5H5)

Guidance literature:: In toluene; under N2 atm. soln. Fe(SPh)(CO)2(η-C5H5) and PMe3 in toluene heatedat reflux for 2.5 h; soln. cooled and filtered, hexane added, ppt. recrystd. by dissolving solid in toluene, adding petroleum ether and chilling, product filtered and dried in vacuo;

Reference yield: 35.0%

: 14104-20-2
silver tetrafluoroborate

: 76452-71-6
Fe(SPh)(CO)(PMe3)(η-C5H5)

: 76452-85-2
(Fe(SPh)(CO)(PMe3)(η-C5H5))BF4

Guidance literature:: In acetone; under N2 atm. Fe(SPh)(CO)(PMe3)(η-C5H5) and AgBF4 dissolved in deaerated acetone and stirred for 10 min; soln. filtered, ethyl ether added and soln. chilled at -20°C overnight, solid filtered and recrystd. from the same solvent mixt.; elem. anal.;

Reference yield: 29.0%

: 14104-20-2
silver tetrafluoroborate

: 76452-71-6
Fe(SPh)(CO)(PMe3)(η-C5H5)

: 594-09-2
trimethylphosphane

: C₅H₅Fe(P(CH₃)3)2SC₆H₅⁽¹⁺⁾*BF₄^(1-)

Guidance literature:: In tetrahydrofuran; byproducts: Ag; Irradiation (UV/VIS); A soln. of complex and PMe3 in THF was irradiated at 67°C for 13.5 h, filtered, evapd., dissolved in acetone, AgBF4 was added (N2 atm.);; filtered, washed with acetone, reduced in vol., Et2O was added; recrystd. from CH2Cl2-Et2O; elem. anal.;;
DOI:10.1016/S0022-328X(00)93466-1