Zinc, dihexyl-

Base Information

• Chemical Name: Zinc, dihexyl-
• CAS No.: 13822-55-4
• Molecular Formula: C12 H26 Zn
• Molecular Weight: 235.728
• DSSTox Substance ID: DTXSID40452660
• Mol file: 13822-55-4.mol

Synonyms:Zinc, dihexyl-;13822-55-4;DTXSID40452660

Chemical Property of Zinc, dihexyl-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 6
• Exact Mass: 234.132593
• Heavy Atom Count: 13
• Complexity: 16

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCC[CH2-].CCCCC[CH2-].[Zn+2]

Technology Process of Zinc, dihexyl-

There total 1 articles about Zinc, dihexyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-hexene (592-41-6,25067-06-5) → hexane (110-54-3) + di(n-hexyl)zinc (13822-55-4)

Guidance literature:

With zinc hydride; Zr catalyst; In toluene; at 80 ℃; for 3h; Product distribution; catalyzed hydrozincation of olefins by ZnCl₂, oxidation of organozinc compounds formed by O₂;

DOI:10.1007/BF00956175

Reference yield: 46.0%

di(n-hexyl)zinc (13822-55-4) → dodecane (112-40-3) + 1-N,N-difluoroaminohexane (18338-65-3) + 2-N,N-difluoroaminohexane (18338-64-2)

Guidance literature:

With nitrogen trifluoride; In diethyl ether; at 0 - 20 ℃;

DOI:10.1016/j.jfluchem.2015.03.013

Reference yield: 40.0%

di(n-hexyl)zinc (13822-55-4) + (2S,3R)-4-(tert-butyldiphenylsilyloxy)-2,3-epoxybutan-1-al (153151-50-9) → (R)-1-[(2R,3R)-3-(tert-Butyl-diphenyl-silanyloxymethyl)-oxiranyl]-heptan-1-ol (522615-47-0)

Guidance literature:

With titanium(IV) isopropylate; C,C,C-trifluoro-N-(2-trifluoromethanesulfonylaminocyclohexyl)methanesulfonamide; In toluene; at -10 ℃; for 20h;

DOI:10.1016/S0040-4039(02)02526-1

upstream raw materials:

1-hexene

Downstream raw materials:

(R)-1-phenylheptanol

(S)-(-)-1-phenyl-1-heptanol

hexan-1-amine

(R)-1-[(2R,3R)-3-(tert-Butyl-diphenyl-silanyloxymethyl)-oxiranyl]-heptan-1-ol

Refernces