HC[(CMe)(N-2,6-iPr₂C₆H₃)]2Al(C(C₂(SiMe₃)2)C(O)C(SiMe₃)C(SiMe₃))

Base Information

• Chemical Name: HC[(CMe)(N-2,6-iPr₂C₆H₃)]2Al(C(C₂(SiMe₃)2)C(O)C(SiMe₃)C(SiMe₃))
• CAS No.: 934009-04-8
• Molecular Formula: C₄₇H₇₇AlN₂OSi₄
• Molecular Weight: 825.465
• Mol file: 934009-04-8.mol

Synonyms:

Chemical Property of HC[(CMe)(N-2,6-iPr₂C₆H₃)]2Al(C(C₂(SiMe₃)2)C(O)C(SiMe₃)C(SiMe₃))

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of HC[(CMe)(N-2,6-iPr₂C₆H₃)]2Al(C(C₂(SiMe₃)2)C(O)C(SiMe₃)C(SiMe₃))

There total 3 articles about HC[(CMe)(N-2,6-iPr₂C₆H₃)]2Al(C(C₂(SiMe₃)2)C(O)C(SiMe₃)C(SiMe₃)) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

HC[(CMe)(N(2,6-iPr2C6H3))2 aluminium (C3O(SiMe3)2) (889111-73-3) + water (7732-18-5) → (HC[(CMe)(N-2,6-iPr2C6H3)]2)Al(OH)2 (552812-70-1) + HC[(CMe)(N-2,6-iPr2C6H3)]2Al(C(C2(SiMe3)2)C(O)C(SiMe3)C(SiMe3)) (934009-04-8)

Guidance literature:

In hexane; toluene; addn. of soln. of water in toluene to soln. of aluminium compd. in hexane at -78°C, warming to room temp.; evapn., recrystn. (hexane) at -20°C to yield first product, elem.anal.; repeating recrystn. (hexane) to yield second product, NMR;

DOI:10.1021/om070028k

Reference yield: 50.0%

HC[(CMe)(N(2,6-iPr2C6H3))2 aluminium (C3O(SiMe3)2) (889111-73-3) + tert-butyl alcohol (75-65-0) → HC[(CMe)(N-2,6-iPr2C6H3)]2Al(OH)(O-tert-Bu) (934009-06-0) + HC[(CMe)(N-2,6-iPr2C6H3)]2Al(C(C2(SiMe3)2)C(O)C(SiMe3)C(SiMe3)) (934009-04-8)

Guidance literature:

In hexane; toluene; addn. of soln. of tert-butanol in toluene to soln. of aluminium compd. in hexane at -78°C, warming to room temp.; evapn., recrystn. (hexane) at -20°C to yeild first product, elem.anal.;

DOI:10.1021/om070028k

Reference yield: 50.0%

ethanol (64-17-5) + HC[(CMe)(N(2,6-iPr2C6H3))2 aluminium (C3O(SiMe3)2) (889111-73-3) → HC[(CMe)(N-2,6-iPr2C6H3)]2Al(OH)(OEt) (934009-05-9) + HC[(CMe)(N-2,6-iPr2C6H3)]2Al(C(C2(SiMe3)2)C(O)C(SiMe3)C(SiMe3)) (934009-04-8)

Guidance literature:

In hexane; toluene; addn. of soln. of ethanol in toluene to soln. of aluminium compd. in hexane at -78°C, warming to room temp.; evapn., recrystn. (hexane) at -20°C to yeild first product, elem.anal.;

DOI:10.1021/om070028k

upstream raw materials:

HC[(CMe)(N(2,6-iPr₂C₆H₃))2 aluminium (C₃O(SiMe₃)2)

water

tert-butyl alcohol

ethanol