(4S)-Methyl 4-(benzyloxy)-2--(2E)-pentenoate

Base Information

Chemical Name:(4S)-Methyl 4-(benzyloxy)-2--(2E)-pentenoate
CAS No.:149287-47-8
Molecular Formula:C₁₅H₁₉NO₅
Molecular Weight:293.32
Hs Code.:

(4S)-Methyl 4-(benzyloxy)-2-<N-(methoxycarbonyl)amino>-(2E)-pentenoate

Synonyms:

Suppliers and Price of (4S)-Methyl 4-(benzyloxy)-2--(2E)-pentenoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (4S)-Methyl 4-(benzyloxy)-2--(2E)-pentenoate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (4S)-Methyl 4-(benzyloxy)-2--(2E)-pentenoate

There total 4 articles about (4S)-Methyl 4-(benzyloxy)-2--(2E)-pentenoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 143995-55-5
2--2-methoxyethanoate

: 149287-47-8
(4S)-Methyl 4-(benzyloxy)-2--(2E)-pentenoate

Guidance literature:: Multi-step reaction with 2 steps

1: 1) phosphorus trichloride / 1) toluene, 70 deg C, 18 h, 2) 2 h, 70 deg C

2: iPr₂NLi / tetrahydrofuran / 2 h / -78 to 24 deg C

With lithium diisopropyl amide; phosphorus trichloride; In tetrahydrofuran;
DOI:10.1021/jo00068a047

Reference yield:

: 100-39-0
benzyl bromide

: 149287-47-8
(4S)-Methyl 4-(benzyloxy)-2--(2E)-pentenoate

Guidance literature:: Multi-step reaction with 3 steps

1: 1) NaH, 2) nBu₄NI / 1) THF, 0 deg C, 15 min, 2) 0 to 24 deg C, 30 min

2: 97 percent / iBu₂AlH / hexane; diethyl ether / -78 °C

3: iPr₂NLi / tetrahydrofuran / 2 h / -78 to 24 deg C

With tetra-(n-butyl)ammonium iodide; sodium hydride; diisobutylaluminium hydride; lithium diisopropyl amide; In tetrahydrofuran; diethyl ether; hexane;
DOI:10.1021/jo00068a047

Reference yield:

: 77287-11-7
methyl (S)-2-(benzyloxy)propanoate

: 149287-47-8
(4S)-Methyl 4-(benzyloxy)-2--(2E)-pentenoate

Guidance literature:: Multi-step reaction with 2 steps

1: 97 percent / iBu₂AlH / hexane; diethyl ether / -78 °C

2: iPr₂NLi / tetrahydrofuran / 2 h / -78 to 24 deg C

With diisobutylaluminium hydride; lithium diisopropyl amide; In tetrahydrofuran; diethyl ether; hexane;
DOI:10.1021/jo00068a047