dicarbonylbis(trifluoromethanesulphonato)bis(triphenylphosphine)ruthenium(II)

Base Information

• Chemical Name: dicarbonylbis(trifluoromethanesulphonato)bis(triphenylphosphine)ruthenium(II)
• CAS No.: 113474-34-3
• Molecular Formula: C₄₀H₃₀F₆O₈P₂RuS₂
• Molecular Weight: 979.813
• Mol file: 113474-34-3.mol

Synonyms:

Chemical Property of dicarbonylbis(trifluoromethanesulphonato)bis(triphenylphosphine)ruthenium(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of dicarbonylbis(trifluoromethanesulphonato)bis(triphenylphosphine)ruthenium(II)

There total 6 articles about dicarbonylbis(trifluoromethanesulphonato)bis(triphenylphosphine)ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

dicarbonyldichlorobis(triphenylphosphine)ruthenium(II) (32240-63-4,29079-66-1,15709-57-6,36500-84-2,15709-73-6,14564-35-3) + silver trifluoromethanesulfonate (2923-28-6) → dicarbonylbis(trifluoromethanesulphonato)bis(triphenylphosphine)ruthenium(II) (105811-82-3,113474-34-3)

Guidance literature:

In toluene; (N2); addn. of silver salt to a soln. of rukthenium complex in CH2Cl2, refluxing for 1 h, cooling to room temp.; filtration, concn., addn. of heptane, cooling to 0°C for 12 h, filtration, washing with heptane, drying in vac.;

DOI:10.1016/S0020-1693(02)00796-X

Reference yield: 55.0%

tricarbonylbis(triphenylphosphine)ruthenium(0) (20332-49-4,14741-36-7) + trifluorormethanesulfonic acid (1493-13-6) → dicarbonylbis(trifluoromethanesulphonato)bis(triphenylphosphine)ruthenium(II) (105811-82-3,113474-34-3)

Guidance literature:

In benzene; reflux for 1 h; cooled, filtered, diluted with methanol, concd., filtered off, washed with diethyl ether and light petroleum, crystd. from CH2Cl2/n-hexane; elem. anal.;

DOI:10.1039/DT9880000415

Reference yield: 40.0%

[Ru(CO)3(triphenylphosphine)2] (14741-36-7,20332-49-4) + trifluorormethanesulfonic acid (1493-13-6) → dicarbonylbis(trifluoromethanesulphonato)bis(triphenylphosphine)ruthenium(II) (105811-82-3,113474-34-3)

Guidance literature:

In toluene; (N2); addn. of acid to a suspn. of ruthenium complex in toluene, refluxing for 1 h, cooling to room temp.; filtration, washing with methanol, drying in vac.; elem. anal.;

DOI:10.1016/S0020-1693(02)00796-X

upstream raw materials:

aqua(carbonyl)bis(trifluoromethanesulphonato)bis(triphenylphosphine)ruthenium(II)

tricarbonylbis(triphenylphosphine)ruthenium⁽⁰⁾

trifluorormethanesulfonic acid

carbonyl bis(hydrido)tris(triphenylphosphine)ruthenium(II)

Refernces

• 1、 Harding, Alexander P.,Robinson, Stephen D.,Henrick, Kim. "Complexes of the Platinum Metals. Part 33. Synthesis of Some Ruthenium and Osmium Sulphonate Derivatives: X-Ray Crystal Structure of Aqua(carbonyl)bis(toluene-p-sulphonato)bis(triphenylphosphine)ruthenium(II)". . p. 415 - 420. Retrieved 2007/10/02.