Carbon monoxide;hydride;ruthenium(2+);triphenylphosphane

Base Information

• Chemical Name: Carbon monoxide;hydride;ruthenium(2+);triphenylphosphane
• CAS No.: 25360-32-1
• Molecular Formula: C₅₅H₄₇OP₃Ru
• Molecular Weight: 917.969
• Hs Code.: 28439000
• European Community (EC) Number: 625-484-6
• Mol file: 25360-32-1.mol

Synonyms:25360-32-1;MFCD00015870;Carbonyl(dihydrido)tris(triphenylphosphine)ruthenium(II);C2251;Carbonyl(dihydrido)tris(triphenylphosphine)ruthenium(II), 99%

Chemical Property of Carbon monoxide;hydride;ruthenium(2+);triphenylphosphane

Chemical Property:

• Appearance/Colour: White to off-white powder
• Vapor Pressure: 4.74E-05mmHg at 25°C
• Melting Point: 161-163 °C(lit.)
• Boiling Point: 360°C at 760 mmHg
• Flash Point: 181.7°C
• PSA: 40.77000
• LogP: 10.12640
• Storage Temp.: Refrigerator
• Sensitive.: Moisture Sensitive
• Water Solubility.: Insoluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 9
• Exact Mass: 918.188317
• Heavy Atom Count: 60
• Complexity: 212

Purity/Quality:

99% ^*data from raw suppliers

Carbonyldihydrotris(triphenylphosphine)ruthenium(II) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 20/21/22
• Safety Statements: 36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [H-].[H-].[C-]#[O+].C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Ru+2]
• Uses: &bull Catalyst for conversion of 1,4-alkynediols into pyrroles &bull Catalyst for oxidation of primary alcohols to methyl esters &bull Catalyst for rearrangement of oximes to amides &bull Catalyst for C-C coupling via directed C-H activation &bull Cata Carbonyldihydrotris(triphenylphosphine)ruthenium(II) is a catalyst used in the preparation of ruthenium (diphenylphosphino)ethyl)amine complexes pre-catalysts for hydrogenation and dehydrogenation. Catalyst for conversion of 1,4-alkynediols into pyrroles Catalyst for oxidation of primary alcohols to methyl esters Catalyst for rearrangement of oximes to amides Catalyst for C-C coupling via directed C-H activation Catalyst for enyne cyclization

Technology Process of Carbon monoxide;hydride;ruthenium(2+);triphenylphosphane

There total 44 articles about Carbon monoxide;hydride;ruthenium(2+);triphenylphosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

(carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II) (157072-60-1,61521-25-3,166941-05-5,16971-33-8) → carbonyl bis(hydrido)tris(triphenylphosphine)ruthenium(II) (25360-32-1,22337-78-6)

Guidance literature:

With triphenylphosphine; In 2-methoxy-ethanol; A soln. of reagents was heated under reflux for 20 min, cooled in an ice-bath;; ppt. was filtered, wshed with EtOH, H2O, EtOH again, dissolved in CH2Cl2, evapd.;;

DOI:10.1016/S0022-328X(00)93469-7

Reference yield: 85.0%

tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4) + 1-indene (95-13-6) → carbonyl bis(hydrido)tris(triphenylphosphine)ruthenium(II) (25360-32-1,22337-78-6) + (η5-indenyl)ruthenium(bis(triphenylphosphine))chloride

Guidance literature:

With KOH; In ethanol; soln. of KOH in EtOH added to refluxing suspn. of Ru complex and indenein EtOH under N2, refluxed for 4 h; cooled, filtered, extd. (CH2Cl2), filtered, added MeOH, ppt. filtered after 30 min, washed with MeOH, Et2O, dried in vac.; purified by extn. (acetone), evapd., recrystd. (CH2Cl2/Et2O); elem. anal.;

DOI:10.1016/0022-328X(85)88033-5

Reference yield: 72.0%

[RuH(OCOMe)(PPh3)3] (25087-75-6,311819-28-0,55354-87-5) + sodium [2-(dimethylamino)ethyl]cyclopentadienide → carbonyl bis(hydrido)tris(triphenylphosphine)ruthenium(II) (25360-32-1,22337-78-6) + [(CpCH2CH2NMe2)RuH(PPh3)2] (249303-20-6)

Guidance literature:

In methanol; Ar-atmosphere; refluxing for 45 min; cooling, filtration, evapn., extn. (Et2O), addn. of hexane, concn., crystn. on standing, collection (filtration), washing (pentane), drying (vac.); elem. anal.;

DOI:10.1021/om990301l

upstream raw materials:

tris(triphenylphosphine)ruthenium(II) chloride

dihydridotetrakis(triphenylphosphine)ruthenium

butyl butyrate

phenyl decanoate

Downstream raw materials:

tricarbonylbis(triphenylphosphine)ruthenium⁽⁰⁾

hydridocarbonylbis(triphenylphosphine)ruthenium(II)(butyrato)

aqua(carbonyl)bis(trifluoromethanesulphonato)bis(triphenylphosphine)ruthenium(II)

{hydrido-trans-(triphenylphosphine)2(carbonyl)(TCD)ruthenium(II)}

Refernces

• 1、 Lorusso, Patrizia,Eastham, Graham R.,Cole-Hamilton, David J.. "Insight into the mechanism of decarbonylation of methanol by ruthenium complexes; a deuterium labelling study". . p. 9411 - 9417. Retrieved 2018/07/29.
• 2、 Grounds, Helen,Anderson, James C.,Hayter, Barry,Blake, Alexander J.. "A new oxidative addition of ruthenium(O) into an aryl halide bond and subsequent intermolecular C-H insertion". . p. 5289 - 5292. Retrieved 2010/01/29.