Technology Process of bis-{N-[3-(2,2'-dipyridin-4-yl)phenyl]}-9,18,-methano-1,8-naphthalimido[b,f][1,5]diazocene
There total 6 articles about bis-{N-[3-(2,2'-dipyridin-4-yl)phenyl]}-9,18,-methano-1,8-naphthalimido[b,f][1,5]diazocene which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
trifluoroacetic acid;
at 20 ℃;
for 18h;
Inert atmosphere;
DOI:10.1039/c2cc17274g
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: ammonium acetate / water / 5 h / Reflux
2.1: palladium 10% on activated carbon / ethanol / 1 h / Reflux
2.2: 1 h / Reflux
3.1: ethanol / 48 h / Reflux
4.1: palladium 10% on activated carbon / N,N-dimethyl-formamide / 1 h / 100 °C
4.2: 4 h / Reflux
5.1: trifluoroacetic acid / 18 h / 20 °C / Inert atmosphere
With
palladium 10% on activated carbon; ammonium acetate; trifluoroacetic acid;
In
ethanol; water; N,N-dimethyl-formamide;
DOI:10.1039/c2cc17274g
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: sodium hydroxide / ethanol; water / 3 h / 0 °C
2.1: ammonium acetate / water / 5 h / Reflux
3.1: palladium 10% on activated carbon / ethanol / 1 h / Reflux
3.2: 1 h / Reflux
4.1: ethanol / 48 h / Reflux
5.1: palladium 10% on activated carbon / N,N-dimethyl-formamide / 1 h / 100 °C
5.2: 4 h / Reflux
6.1: trifluoroacetic acid / 18 h / 20 °C / Inert atmosphere
With
palladium 10% on activated carbon; ammonium acetate; trifluoroacetic acid; sodium hydroxide;
In
ethanol; water; N,N-dimethyl-formamide;
DOI:10.1039/c2cc17274g
