Pt3(μ2-CO)3(benzyldiphenylphosphine)3

Base Information

Chemical Name:Pt3(μ2-CO)3(benzyldiphenylphosphine)3
CAS No.:15683-57-5
Molecular Formula:C₆₀H₅₁O₃P₃Pt₃
Molecular Weight:1498.22
Hs Code.:

Synonyms:

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Chemical Property of Pt3(μ2-CO)3(benzyldiphenylphosphine)3

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Technology Process of Pt3(μ2-CO)3(benzyldiphenylphosphine)3

There total 1 articles about Pt3(μ2-CO)3(benzyldiphenylphosphine)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: PtCl₂(1,5-cyclooctadiene)

: 201230-82-2
carbon monoxide

: 7650-91-1
benzyldiphenylphosphane

: 15683-57-5
Pt3(μ2-CO)3(benzyldiphenylphosphine)3

: [Pt3(μ-CO)3(P(CH2Ph)Ph2)4]

Guidance literature:: With potassium hydroxide; dihydrogen peroxide; In tetrahydrofuran; ethanol; water; in N2 atmosphere PtCl2(cyclooctadiene) suspended in C2H5OH-THF, treatedwith diphenylbenzylphosphine, stirred for 3 hs; CO bubbled through, excess KOH in H2O added, stirred for 2 hs; solvent partially removed under reduced pressure, solid removed; washed with water, ethanol, dried in vac., dissolved in CH2Cl2, filtered through silica gel, eluted with diethyl ether, evapd., CH2Cl2, acetoneadded, H2O2 added at 40 °C, cooled at 0 °C, evapd. under reduced pressure, pttn.; elem. anal.;
DOI:10.1016/S0020-1693(99)00523-X

Reference yield: 87.0%

: 15683-57-5
Pt3(μ2-CO)3(benzyldiphenylphosphine)3

: 201230-82-2
carbon monoxide

: 844681-12-5
[Pt5(CO)(μ-CO)5(PBzPh2)4]

Guidance literature:: With H₂O₂; In tetrahydrofuran; water; soln. (Pt3(μ-CO)3(PBzPh2)3) in THF was stirred with excess CO at roomtemp. and treated with 30 % H2O2, stirred for 2 days; soln. was evapd. to dryness in vacuo, residue was dissolved in toluene, filtered through neutral alumina pad and concd., n-heptane was added, recrystn. from CH2Cl2-heptane; elem. anal.;
DOI:10.1016/j.ica.2004.06.056

Reference yield: 86.0%

: 15683-57-5
Pt3(μ2-CO)3(benzyldiphenylphosphine)3

: 7446-09-5,12143-17-8,89125-89-3
sulfur dioxide

: [Pt3(μ-SO2)3(PPh2Bz)3]

Guidance literature:: In hexane; benzene; in pure dry N2 atmosphere Pt3(CO)3(PPh2Bz)3 dissolved in benzene, SO2 added for 20 hs, volume reduced in vac., hexane added, cooled at 0 °C; ppt. filtered, washed with cold benzene, hexane, dried in vac.; elem. anal.;
DOI:10.1016/S0020-1693(99)00523-X