Technology Process of [N(PPh3)2][2-Br-2,2,2-(CO)3-3-NMe3-closo-2,1-MoCB10H10]
There total 1 articles about [N(PPh3)2][2-Br-2,2,2-(CO)3-3-NMe3-closo-2,1-MoCB10H10] which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
n-BuLi;
In
tetrahydrofuran; hexane; acetonitrile;
under N2 atm. to suspn. 7-Me3N-nido-7-CB10H12 in THF at -40°C wasadded BuLi in hexane, warmed to -10°C, (Mo(CO)3(NCMe)3) (prepare d in situ from (Mo(CO)6) and MeCN) was added, warmed to room temp., stirred for 1 h, CH2CHCH2Br was added; react. mixt. was stirred overnight, PPNCl was added and stirred for 3 h,filtered, filtrate was evapd. in air, crystals were washed with ice-col d acetone and dried in vacuo; elem. anal.;
DOI:10.1021/ic020091w
- Guidance literature:
-
With
Tl[PF6];
In
dichloromethane;
under N2 atm. mixt. (PPN)(2-Br-2,2,2-(CO)3-3-NMe3-closo-2,1-MoCB10H10), PPh3, and Tl(PF6) was stirred in CH2Cl2 for 12 h; react. mixt. was filtered, solvent was removed, residue was taken in CH2Cl2 and chromed. (CH2Cl2-petroleum ether 3:1); elem. anal.;
DOI:10.1021/ic020091w
