2,4-bis(p-dodecylphenylamino)-6-chloro-1,3,5-triazine

Base Information

• Chemical Name: 2,4-bis(p-dodecylphenylamino)-6-chloro-1,3,5-triazine
• CAS No.: 78795-50-3
• Molecular Formula: C₃₉H₆₀ClN₅
• Molecular Weight: 634.392
• Mol file: 78795-50-3.mol

Synonyms:

Chemical Property of 2,4-bis(p-dodecylphenylamino)-6-chloro-1,3,5-triazine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,4-bis(p-dodecylphenylamino)-6-chloro-1,3,5-triazine

There total 4 articles about 2,4-bis(p-dodecylphenylamino)-6-chloro-1,3,5-triazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,3,5-trichloro-2,4,6-triazine (108-77-0) + 4-dodecylaniline (104-42-7) → 2,4-bis(p-dodecylphenylamino)-6-chloro-1,3,5-triazine (78795-50-3)

Guidance literature:

With N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; at 0 - 20 ℃; for 13h; Inert atmosphere;

DOI:10.1021/ja302574b

Reference yield:

1-(dodec-1-yn-1-yl)-4-nitrobenzene (1022975-57-0) → 2,4-bis(p-dodecylphenylamino)-6-chloro-1,3,5-triazine (78795-50-3)

Guidance literature:

Multi-step reaction with 2 steps

1: 5%-palladium/activated carbon; hydrogen / ethanol; ethyl acetate / 24 h / 20 °C / 15001.5 Torr / Autoclave

2: N-ethyl-N,N-diisopropylamine / tetrahydrofuran / 13 h / 0 - 20 °C / Inert atmosphere

With 5%-palladium/activated carbon; hydrogen; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; ethanol; ethyl acetate;

DOI:10.1021/ja302574b

Reference yield:

p-nitrobenzene iodide (636-98-6) → 2,4-bis(p-dodecylphenylamino)-6-chloro-1,3,5-triazine (78795-50-3)

Guidance literature:

Multi-step reaction with 3 steps

1: copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; triethylamine / 2 h / 80 °C / Inert atmosphere

2: 5%-palladium/activated carbon; hydrogen / ethanol; ethyl acetate / 24 h / 20 °C / 15001.5 Torr / Autoclave

3: N-ethyl-N,N-diisopropylamine / tetrahydrofuran / 13 h / 0 - 20 °C / Inert atmosphere

With copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; 5%-palladium/activated carbon; hydrogen; triethylamine; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; ethanol; ethyl acetate;

DOI:10.1021/ja302574b

upstream raw materials:

p-nitrobenzene iodide

1,3,5-trichloro-2,4,6-triazine

4-dodecylaniline

1-(dodec-1-yn-1-yl)-4-nitrobenzene

Downstream raw materials:

2-amino-4,6-bis[4-(dodecyl)phenylamino]-1,3,5-triazine