diacetate{(R)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl}palladium(II)

Base Information

• Chemical Name: diacetate{(R)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl}palladium(II)
• CAS No.: 430431-28-0
• Molecular Formula: C₄₈H₃₈O₄P₂Pd
• Molecular Weight: 847.195
• Mol file: 430431-28-0.mol

Synonyms:

Chemical Property of diacetate{(R)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl}palladium(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of diacetate{(R)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl}palladium(II)

There total 3 articles about diacetate{(R)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl}palladium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

palladium diacetate (3375-31-3) + (R)-2,2'-bis(diphenylphosphanyl)-1,1'-binaphthyl (76144-87-1,76189-55-4,76189-56-5,98327-87-8,136655-44-2) → diacetate{(R)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl}palladium(II) (430431-28-0,331749-09-8)

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 1h; Inert atmosphere; Schlenk technique; Glovebox;

DOI:10.1021/jacs.1c04965

Reference yield:

(R)-(+)-2,2’-bis(diphenylphosphino)-1,1’-binaphthalene (76189-55-4,76189-56-5,98327-87-8) + palladium(II) acetate trimer (53189-26-7) → bis{(R)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl}palladium(O) + diacetate{(R)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl}palladium(II) (430431-28-0,331749-09-8)

Guidance literature:

With 1,8-bis(dimethylamino)naphthalene or aliph. amines; In water; benzene; byproducts: (R)-2-P(C6H5)2-2'-PO(C6H5)2-1,1'-binaphthyl; heating Pd(CH3CO2)2 and ligand in soln. of naphthalene (proton sponge) or aliph. amines in benzene satd. with H2O at 40°C in NMR tube, 10-40 h; mechanism discussed;; not isolated; detn. by NMR spectroscopy;;

DOI:10.1246/cl.1992.2177

Reference yield:

(R)-(+)-2,2’-bis(diphenylphosphino)-1,1’-binaphthalene (76189-55-4,76189-56-5,98327-87-8) + palladium(II) acetate trimer (53189-26-7) → diacetate{(R)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl}palladium(II) (430431-28-0,331749-09-8)

Guidance literature:

With water; triethylamine; In benzene; Pd-compd., ligand and N(C2H5)3 dissolved in benzene at room temp.;; detn. by IR and NMR spectroscopy; elem. anal.;;

DOI:10.1246/cl.1992.2177

upstream raw materials:

(R)-(+)-2,2’-bis(diphenylphosphino)-1,1’-binaphthalene

palladium(II) acetate trimer

palladium diacetate

(R)-2,2'-bis(diphenylphosphanyl)-1,1'-binaphthyl