1,2-bis(3,5-bis(trifluoromethyl)phenylimino)acenaphthenemethylchloropalladium(II)

Base Information

• Chemical Name: 1,2-bis(3,5-bis(trifluoromethyl)phenylimino)acenaphthenemethylchloropalladium(II)
• CAS No.: 674322-92-0
• Molecular Formula: C₂₉H₁₅ClF₁₂N₂Pd
• Molecular Weight: 761.305
• Mol file: 674322-92-0.mol

Synonyms:

Chemical Property of 1,2-bis(3,5-bis(trifluoromethyl)phenylimino)acenaphthenemethylchloropalladium(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,2-bis(3,5-bis(trifluoromethyl)phenylimino)acenaphthenemethylchloropalladium(II)

There total 4 articles about 1,2-bis(3,5-bis(trifluoromethyl)phenylimino)acenaphthenemethylchloropalladium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

chloromethyl(1,5-cyclooctadiene)palladium(II) + N,N'-bis(bis(3,5-trifluoromethyl)phenyl)acenaphthenequinonediimine (226071-21-2) → 1,2-bis(3,5-bis(trifluoromethyl)phenylimino)acenaphthenemethylchloropalladium(II) (674322-92-0)

Guidance literature:

In dichloromethane; (Ar); using Schlenk techniques; addn. of 1.1 equiv. of C10H6(CNC6H3(CF3)2)2 to PdCl(COD)Me in CH2Cl2 at room temp. for 1 h according to: Milani,B.; Marson,A.; Zangrando,E.; Mestroni,G.; Ernsting,J.M.; Elsevier,C. J. Inorg. Chim. Acta 2002, 327, 188-201; addn. of Et2O; pptn., elem. anal.;

DOI:10.1021/om7011858

Reference yield: 8.2%

N,N'-bis(bis(3,5-trifluoromethyl)phenyl)acenaphthenequinonediimine (226071-21-2) + trans-dichlorobis(dimethylsulfide)palladium(II) (14567-23-8) + methyllithium (917-54-4) → 1,2-bis(3,5-bis(trifluoromethyl)phenylimino)acenaphthenemethylchloropalladium(II) (674322-92-0) + bis(μ2-1,2-bis(3,5-bis(trifluoromethyl)phenylimino)acenaphthene)bis(dimethylsulfide)methylchlorotripalladium*diethyl ether*0.5pentane

Guidance literature:

In diethyl ether; (Ar); addn. of ethereal soln. of methyllithium to suspn. of palladium compd. in ether at -60°C, warming to -40°C, addn. of methanol, keeping for 10 min, addn. of acenaphthene deriv. at -40°C, warming to room temp., stirring for 2 h; evapn., extn. (diethyl ether), keeping at -20°C, isolation of crystals, elem. anal., keeping mother liquor at -20°C, isolation of crystals, X-ray anal.;

DOI:10.1002/zaac.200800056

Reference yield:

N,N'-bis(bis(3,5-trifluoromethyl)phenyl)acenaphthenequinonediimine (226071-21-2) + [Pd(CH3)Cl(bis(3,5-(CH3)2C6H3)acenaphthenequinonediimine)] (674322-80-6) → α-diimine N,N′-bis(3,5-dimethylphenylimino)acenaphthenequinonate (444798-21-4) + 1,2-bis(3,5-bis(trifluoromethyl)phenylimino)acenaphthenemethylchloropalladium(II) (674322-92-0)

Guidance literature:

In chloroform-d1; 1 equiv. of the free ligand was added to a CDCl3 soln. of Pd-complex at 20°C, reaction was monitored by (1)H NMR spectroscopy; equil. const. is given; (1)H NMR spectral data;

DOI:10.1021/om034370i

upstream raw materials:

N,N'-bis(bis(3,5-trifluoromethyl)phenyl)acenaphthenequinonediimine

[Pd(CH₃)Cl(bis(3,5-(CH₃)2C₆H₃)acenaphthenequinonediimine)]

trans-dichlorobis(dimethylsulfide)palladium(II)

methyllithium

Downstream raw materials:

[PdCl(acetonitrile)(bis(3,5-(CF₃)2C₆H₃)acenaphthenequinonediimine)][PF₆]