Benzenamine, N,N'-1,2-acenaphthylenediylidenebis[3,5-bis(trifluoromethyl)-

Base Information

• Chemical Name: Benzenamine, N,N'-1,2-acenaphthylenediylidenebis[3,5-bis(trifluoromethyl)-
• CAS No.: 226071-21-2
• Molecular Formula: C28H12F12N2
• Molecular Weight: 604.398
• Mol file: 226071-21-2.mol

Synonyms:

Chemical Property of Benzenamine, N,N'-1,2-acenaphthylenediylidenebis[3,5-bis(trifluoromethyl)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzenamine, N,N'-1,2-acenaphthylenediylidenebis[3,5-bis(trifluoromethyl)-

There total 3 articles about Benzenamine, N,N'-1,2-acenaphthylenediylidenebis[3,5-bis(trifluoromethyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

[ZnCl2(bis(3,5-bis(trifluoromethyl)phenyl)acenaphthenequinonediimine)] (798567-18-7) + potassium oxalate (583-52-8) → N,N'-bis(bis(3,5-trifluoromethyl)phenyl)acenaphthenequinonediimine (226071-21-2) + zinc(II) oxalate (547-68-2)

Guidance literature:

In dichloromethane; water; Zn complex was suspended in CH2Cl2 and soln. potassium oxalate in water was added, shaked for 5 min;

DOI:10.1021/om020147u

Reference yield:

3,5-Bis-(trifluoromethyl)aniline (328-74-5) + acenaphthene quinone (82-86-0) → N,N'-bis(bis(3,5-trifluoromethyl)phenyl)acenaphthenequinonediimine (226071-21-2)

Guidance literature:

3,5-Bis-(trifluoromethyl)aniline; acenaphthene quinone; With acetic acid; zinc(II) chloride; In toluene; at 120 ℃; for 0.75h; Inert atmosphere;

With water; potassium oxalate; In dichloromethane;

DOI:10.1002/chem.200901126

Reference yield:

C28H12F12N2*Zn(2+)*2Cl(1-) → N,N'-bis(bis(3,5-trifluoromethyl)phenyl)acenaphthenequinonediimine (226071-21-2)

Guidance literature:

With potassium oxalate; In dichloromethane; water;

DOI:10.1039/c6nj02199a

upstream raw materials:

[ZnCl₂(bis(3,5-bis(trifluoromethyl)phenyl)acenaphthenequinonediimine)]

potassium oxalate

3,5-Bis-(trifluoromethyl)aniline

acenaphthene quinone

Downstream raw materials:

(σ-N,σ-N'-bis(3,5-bis(trifluoromethyl)phenylimino)acenaphthene)(η2-maleic anhydride)platinum(0)

(σ-N,σ-N'-bis(3,5-bis(trifluoromethyl)phenylimino)acenaphthene)(η2-tetrcyanoethene)platinum(0)

α-diimine N,N′-bis(3,5-dimethylphenylimino)acenaphthenequinonate

1,2-bis(3,5-bis(trifluoromethyl)phenylimino)acenaphthenemethylchloropalladium(II)