[PdCl(C₆H₂(CH₂SPh)-2,6-(OH)-4)]

Base Information

• Chemical Name: [PdCl(C₆H₂(CH₂SPh)-2,6-(OH)-4)]
• CAS No.: 1070800-09-7
• Molecular Formula: C₂₀H₁₇ClOPdS₂
• Molecular Weight: 479.359
• Mol file: 1070800-09-7.mol

Synonyms:

Chemical Property of [PdCl(C₆H₂(CH₂SPh)-2,6-(OH)-4)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [PdCl(C₆H₂(CH₂SPh)-2,6-(OH)-4)]

There total 3 articles about [PdCl(C₆H₂(CH₂SPh)-2,6-(OH)-4)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

[Pd(C6H2(CH2SPh)-2,6-(OH)-4)(MeCN)]BF4 (1070260-80-8) + sodium chloride (7647-14-5) → [PdCl(C6H2(CH2SPh)-2,6-(OH)-4)] (1070800-09-7,748150-00-7)

Guidance literature:

In water; acetonitrile; (under N2, Schlenk); aq. soln. of NaCl added to MeCN soln. of Pd-complex, stirred for 2 h at ambient temp.; concd. to removed volatiles, residue washed with H2O, dried in vacuo;

DOI:10.1016/j.jorganchem.2008.06.016

Reference yield:

bis(benzonitrile)palladium(II) dichloride (15617-18-2,39958-10-6,14220-64-5) + 3,5-bis[(phenylsulfanyl)methyl]phenol (168414-96-8) → [PdCl(C6H2(CH2SPh)-2,6-(OH)-4)] (1070800-09-7,748150-00-7)

Guidance literature:

With silver tetrafluoroborate; tetrabutyl-ammonium chloride; In dichloromethane; acetonitrile; 1 equiv. of Pd-compd. was added in one portion to S-compd. (in CH2Cl2:MeCN (1:2, v/v) stirring for 30 min under Ar, AgBF4 was added, stirring for 30 min in the dark, solvent was removed in vac., (nBu)4NCl was added in CH2Cl2, stirring for 48 h under Ar; mixt. was passed through an alumina column, solvent was removed;

DOI:10.1016/j.jcat.2004.05.015

Reference yield:

(3,5-Bis-phenylsulfanylmethyl-phenoxy)-tert-butyl-dimethyl-silane (1070260-71-7) → [PdCl(C6H2(CH2SPh)-2,6-(OH)-4)] (1070800-09-7,748150-00-7)

Guidance literature:

Multi-step reaction with 2 steps

1: acetonitrile

2: water; acetonitrile

In water; acetonitrile;

DOI:10.1016/j.jorganchem.2008.06.016

upstream raw materials:

bis(benzonitrile)palladium(II) dichloride

3,5-bis[(phenylsulfanyl)methyl]phenol

[Pd(C₆H₂(CH₂SPh)-2,6-(OH)-4)(MeCN)]BF₄

sodium chloride

Downstream raw materials:

Pd-Cl 3-((3,5-bis(phenylsulfanylmethyl)phenoxy)propyltrimethoxysilane