(S)-1,1'-(1,1'-binaphthyl-2,2'-diyl)ferrocene

Base Information

Chemical Name:(S)-1,1'-(1,1'-binaphthyl-2,2'-diyl)ferrocene
CAS No.:402718-81-4
Molecular Formula:C₃₀H₂₀Fe
Molecular Weight:436.336
Hs Code.:

Synonyms:

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Chemical Property of (S)-1,1'-(1,1'-binaphthyl-2,2'-diyl)ferrocene

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Technology Process of (S)-1,1'-(1,1'-binaphthyl-2,2'-diyl)ferrocene

There total 4 articles about (S)-1,1'-(1,1'-binaphthyl-2,2'-diyl)ferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

: 1,1'-bis(chlorozincio)ferrocene

: 76905-80-1,86688-06-4,86688-07-5
(S)-2,2'-diiodo-1,1'-binaphthyl

: 102-54-5,55404-68-7
ferrocene

: 402718-81-4,151735-76-1
(S)-1,1'-(1,1'-binaphthyl-2,2'-diyl)ferrocene

: 151735-75-0
(C₁₀H₆)2(Fe(C₅H₄)2)2

: 1,1''-biferrocene

Guidance literature:: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; In tetrahydrofuran; a mixt. in THF was stirred for 72 h at room temp. (Ar); poured into 10% aq. HCl, extd. with CH2Cl2, washed with water, dried over MgSO4, solvent was removed in vac., flash chromy. on silica gel (isohexane, isohexane-CH2Cl2); crystd. from hexane;
DOI:10.1016/S0022-328X(01)00926-3

Reference yield: 11.0%

: 70595-34-5
1,1'-bis(trimethylstannyl)ferrocene

: 76905-80-1,86688-06-4,86688-07-5
(S)-2,2'-diiodo-1,1'-binaphthyl

: 402718-81-4,151735-76-1
(S)-1,1'-(1,1'-binaphthyl-2,2'-diyl)ferrocene

: 1,1''-biferrocene

: 60536-98-3,19634-89-0,32587-64-7,32834-84-7
2,2'-dimethyl-1,1'-binaphthyl

: 402718-90-5
2-iodo-2'-methyl-1,1'-binaphthyl

Guidance literature:: With triphenylphosphine; lithium chloride; bis(dibenzylideneacetone)-palladium⁽⁰⁾; In tetrahydrofuran; a soln. of ferrocene in THF was added to a suspn. of biphenyl, PPh3 and LiCl in THF, the mixt. was heated to reflux for 48 h, cooled to room temp. (Ar); diluted with CH2Cl2, washed with 10% aq. HCl, water, with brine, dried over MgSO4, the solvent was removed in vac., chromd. on silica gel (isohexane; isohexane-CH2Cl2);
DOI:10.1016/S0022-328X(01)00926-3

Reference yield: 2.0%

: 12152-94-2,32841-83-1
1,1′-ferrocenediboronic acid

: 76905-80-1,86688-06-4,86688-07-5
(S)-2,2'-diiodo-1,1'-binaphthyl

: 402718-81-4,151735-76-1
(S)-1,1'-(1,1'-binaphthyl-2,2'-diyl)ferrocene

: 604-53-5
1,1'-bisnaphthalene

Guidance literature:: With sodium hydroxide; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; In 1,2-dimethoxyethane; water; DME-H2O/NaOH, reflux, 6 h (Ar);
DOI:10.1016/S0022-328X(01)00926-3