[PtCl(2,6-dimethylphenyl isocyanide)(1,2-bis(bis(phenyl)phosphino)ethane)](BF₄)

Base Information

• Chemical Name: [PtCl(2,6-dimethylphenyl isocyanide)(1,2-bis(bis(phenyl)phosphino)ethane)](BF₄)
• CAS No.: 847800-41-3
• Molecular Formula: BF₄*C₃₅H₃₃ClNP₂Pt
• Molecular Weight: 846.939
• Mol file: 847800-41-3.mol

Synonyms:

Chemical Property of [PtCl(2,6-dimethylphenyl isocyanide)(1,2-bis(bis(phenyl)phosphino)ethane)](BF₄)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of [PtCl(2,6-dimethylphenyl isocyanide)(1,2-bis(bis(phenyl)phosphino)ethane)](BF₄)

There total 1 articles about [PtCl(2,6-dimethylphenyl isocyanide)(1,2-bis(bis(phenyl)phosphino)ethane)](BF₄) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

silver tetrafluoroborate (14104-20-2) + [platinum(II)dichloride(1,2-bis(diphenylphosphino)ethane)] (83095-83-4,14647-25-7) + 2,6-dimethylphenyl isonitrile (119072-54-7,2769-71-3) → [PtCl(2,6-dimethylphenyl isocyanide)(1,2-bis(bis(phenyl)phosphino)ethane)](BF4) (847800-41-3)

Guidance literature:

In dichloromethane; acetone; byproducts: AgCl; (N2); using Schlenk techniques; addn. of soln. of AgBF4 in Me3CO to suspn. of PtCl2(P(C6H5)2CH2CH2P(C6H5)2) in Me3CO and CH2Cl2 with stirring for 20 min, filtration, addn. of 2,6-Me2C6H3NC to filtrate; stirring for 2h at room temp.; concn. under vac., treatment with Et2O, pptn., filtration, washing with Et2O, drying under vac., elem. anal.;

DOI:10.1021/om049264a

upstream raw materials:

silver tetrafluoroborate

[platinum(II)dichloride(1,2-bis(diphenylphosphino)ethane)]

2,6-dimethylphenyl isonitrile