[Cr(CO)5(CNC₆H₄-2-CH₂OSiMe₃)]

Base Information

Chemical Name:[Cr(CO)5(CNC₆H₄-2-CH₂OSiMe₃)]
CAS No.:497152-97-3
Molecular Formula:C₁₆H₁₅CrNO₆Si
Molecular Weight:397.38
Hs Code.:

[Cr(CO)5(CNC<sub>6</sub>H<sub>4</sub>-2-CH<sub>2</sub>OSiMe<sub>3</sub>)]

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Chemical Property of [Cr(CO)5(CNC₆H₄-2-CH₂OSiMe₃)]

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Technology Process of [Cr(CO)5(CNC₆H₄-2-CH₂OSiMe₃)]

There total 1 articles about [Cr(CO)5(CNC₆H₄-2-CH₂OSiMe₃)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 14780-98-4
tetraethylammonium pentacarbonyliodochromate⁽⁰⁾

: 497152-89-3
2-(trimethylsiloxymethyl)phenyl isocyanide

: 497152-97-3
[Cr(CO)5(CNC₆H₄-2-CH₂OSiMe₃)]

Guidance literature:: With silver tetrafluoroborate; In acetone; byproducts: AgI; (N2); standard Schlenk technique; soln. of AgBF4 in acetone was added dropwise over 20 min to suspn. of Cr complex in acetone at 0°C; mixt. was quickly filtered; soln. of isocyanide in acetone was added dropwise to filtrate; stirred for 20 min; warmed to room temp.; concd.; Et2O was added; mixt. stirred for 30 min; filtered; evapd.; residue dissolved in Et2O/C6H14; stirred for 1 h; concd. (vac.); filtered; filtrate evapd.;
DOI:10.1016/S0022-328X(02)01883-1

Reference yield:

: 67-56-1
methanol

: 497152-97-3
[Cr(CO)5(CNC₆H₄-2-CH₂OSiMe₃)]

: 497152-99-5
[Cr(CO)5(CNC₆H₄-2-CH₂OH)]

Guidance literature:: With [n-Bu₄N]F; In methanol; (N2); standard Schlenk technique; n-Bu4NF was added to soln. of Cr complex in MeOH at room temp.; mixt. was stirred for 24 h; evapd.; Et2O and C6H14 added; mixt. stirred at ambient temp. for 1 h; filtered; concd.; filtered; washed (C6H14); dried (vac.); elem. anal.;
DOI:10.1016/S0022-328X(02)01883-1