5-(3,5-di-tert-butylphenyl)-2,8,12,18-tetraethyl-15-(4-(1-imidazolylmethyl)phenyl)-3,7,13,17-tetramethylporphine zinc complex

Base Information

Chemical Name:5-(3,5-di-tert-butylphenyl)-2,8,12,18-tetraethyl-15-(4-(1-imidazolylmethyl)phenyl)-3,7,13,17-tetramethylporphine zinc complex
CAS No.:518297-81-9
Molecular Formula:C₅₆H₆₄N₆Zn
Molecular Weight:886.554
Hs Code.:

Synonyms:

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Chemical Property of 5-(3,5-di-tert-butylphenyl)-2,8,12,18-tetraethyl-15-(4-(1-imidazolylmethyl)phenyl)-3,7,13,17-tetramethylporphine zinc complex

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Technology Process of 5-(3,5-di-tert-butylphenyl)-2,8,12,18-tetraethyl-15-(4-(1-imidazolylmethyl)phenyl)-3,7,13,17-tetramethylporphine zinc complex

There total 2 articles about 5-(3,5-di-tert-butylphenyl)-2,8,12,18-tetraethyl-15-(4-(1-imidazolylmethyl)phenyl)-3,7,13,17-tetramethylporphine zinc complex which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 5-(3,5-di-tert-butylphenyl)-2,8,12,18-tetraethyl-15-(4-(1-imidazolylmethyl)phenyl)-3,7,13,17-tetramethylporphine

: 557-34-6
zinc diacetate

: 518297-81-9
5-(3,5-di-tert-butylphenyl)-2,8,12,18-tetraethyl-15-(4-(1-imidazolylmethyl)phenyl)-3,7,13,17-tetramethylporphine zinc complex

Guidance literature:: In methanol; dichloromethane; a soln. in CH2Cl2 was treated with NaHCO3 and water, concd. in vac., treated with satd. soln. of zinc acetate in methanol, stirred overnight in the dark; washed with water, aq. NaHCO3, water, the extract was dried over Na2SO4,evapd., dried in vac.; repptd. from CH2Cl2-methanol; elem. anal.;
DOI:10.1016/S0020-1693(02)01137-4

Reference yield: 80.0%

: 2206-26-0
[D₃]acetonitrile

: ((C₄H₉)2C₆H₃)(C₃H₃N₂CH₂C₆H₄)(C₂H₅)4(CH₃)4C₂₀H₂N₄ZnCo(CO₂C₄H₇NCH₂)2C₅H₃N⁽¹⁺⁾*ClO₄^(1-)*CH₃COCH₃=C₇₃H₈₅N₉O₄CoZnClO₄*C₃H₆O

: Co(OCOC₄H₇NCH₂)2C₅H₃N(C⁽²⁾H₃CN)⁽¹⁺⁾

: 518297-81-9
5-(3,5-di-tert-butylphenyl)-2,8,12,18-tetraethyl-15-(4-(1-imidazolylmethyl)phenyl)-3,7,13,17-tetramethylporphine zinc complex

Guidance literature:: In chloroform-d1; [D₃]acetonitrile; Irradiation (UV/VIS); a soln. in CDCl3-CD3CN was irradiated with a halogen lamp for 3 min; not sepd., detected by spectra;
DOI:10.1016/S0020-1693(02)01137-4

Reference yield: 51.0%

: Co⁽³⁺⁾*(OCOC₄H₇NCH₂)2C₅H₃N^(2-)*BF₄^(1-)=Co(OCOC₄H₇NCH₂)2C₅H₃NBF₄

: 518297-81-9
5-(3,5-di-tert-butylphenyl)-2,8,12,18-tetraethyl-15-(4-(1-imidazolylmethyl)phenyl)-3,7,13,17-tetramethylporphine zinc complex

: sodium perchlorate

: 67-64-1
acetone

: ((C₄H₉)2C₆H₃)(C₃H₃N₂CH₂C₆H₄)(C₂H₅)4(CH₃)4C₂₀H₂N₄ZnCo(CO₂C₄H₇NCH₂)2C₅H₃N⁽¹⁺⁾*ClO₄^(1-)*CH₃COCH₃=C₇₃H₈₅N₉O₄CoZnClO₄*C₃H₆O

Guidance literature:: In chloroform; acetonitrile; a soln. in CHCl3 was stirred at 60°C in the dark overnight, CH3CNwas added, the mixt. was heated with stirring in the dark for 1 h, evap d., dissolved in CH2Cl2, pptd. with hexane, filtered, dissolved in acetone and water, NaClO4 was added; cooled at 0°C overnight, ppt. was filtered, washed with cold water, dried in vac.; elem. anal.;
DOI:10.1016/S0020-1693(02)01137-4