[Ir(SP(C₆H₅)2C₅HP(CH₃)(C₆H₅)2P(C₆H₅)2S)(P(C₆H₅)3)]

Base Information

• Chemical Name: [Ir(SP(C₆H₅)2C₅HP(CH₃)(C₆H₅)2P(C₆H₅)2S)(P(C₆H₅)3)]
• CAS No.: 850211-40-4
• Molecular Formula: C₆₀H₄₉IrP₄S₂
• Molecular Weight: 1150.3
• Mol file: 850211-40-4.mol

Synonyms:

Chemical Property of [Ir(SP(C₆H₅)2C₅HP(CH₃)(C₆H₅)2P(C₆H₅)2S)(P(C₆H₅)3)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ir(SP(C₆H₅)2C₅HP(CH₃)(C₆H₅)2P(C₆H₅)2S)(P(C₆H₅)3)]

There total 1 articles about [Ir(SP(C₆H₅)2C₅HP(CH₃)(C₆H₅)2P(C₆H₅)2S)(P(C₆H₅)3)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

[Ir(cyclooctene)Cl]2 + methyllithium (917-54-4) + triphenylphosphine (603-35-0) + 2,6-bis(diphenylphosphine sulfide)-3,5-diphenylphosphinine (444154-54-5) → [Ir(SP(C6H5)2C5HP(CH3)(C6H5)2P(C6H5)2S)(P(C6H5)3)] (850211-40-4)

Guidance literature:

In tetrahydrofuran; diethyl ether; (Ar); Schlenk technique; soln. of MeLi in Et2O was syringed into soln. of P-S compd. in THF at -78°C; warmed to room temp. and stirred for 20 min; Ir complex (0.5 equiv.) and PPh3 were added; soln. was stirredfor 2 h;

DOI:10.1021/om049198c

Reference yield: 82.0%

[Ir(SP(C6H5)2C5HP(CH3)(C6H5)2P(C6H5)2S)(P(C6H5)3)] (850211-40-4) + oxygen (80937-33-3) → [(CH3PC5H(C6H5)2(P(S)(C6H5)2)2)Ir(P(C6H5)3)(O2)] (850211-38-0)

Guidance literature:

In tetrahydrofuran; (Ar); Schlenk technique; soln. of Ir complex in THF was stirred under O2(1 atm) for 2 h; filtered; washed (THF, hexane); elem. anal.;

DOI:10.1021/om049198c

Reference yield: 76.0%

[Ir(SP(C6H5)2C5HP(CH3)(C6H5)2P(C6H5)2S)(P(C6H5)3)] (850211-40-4) + hydrogen (1333-74-0) → [Ir(H)2(SP(C6H5)2C5HP(CH3)(C6H5)2P(C6H5)2S)(P(C6H5)3)]

Guidance literature:

In tetrahydrofuran; under Ar, Schlenk technique; H2 (1 atm) bubbled through soln. of Ir complex in THF at room temp. for 3 min; solvent removed; residue washed with hexane and Et2O; dissolved in CH2Cl2; filtered through Celite; dried; elem. anal.;

DOI:10.1021/om050900u

upstream raw materials:

methyllithium

triphenylphosphine

2,6-bis(diphenylphosphine sulfide)-3,5-diphenylphosphinine

Downstream raw materials:

[(CH₃PC₅H(C₆H₅)2(P(S)(C₆H₅)2)2)Ir(P(C₆H₅)3)(O₂)]