O-triphenylantimony(V) di(methylphenyloximate)

Base Information

• Chemical Name: O-triphenylantimony(V) di(methylphenyloximate)
• CAS No.: 75392-03-9
• Molecular Formula: C₃₄H₃₁N₂O₂Sb
• Molecular Weight: 621.382
• Mol file: 75392-03-9.mol

Synonyms:

Chemical Property of O-triphenylantimony(V) di(methylphenyloximate)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of O-triphenylantimony(V) di(methylphenyloximate)

There total 6 articles about O-triphenylantimony(V) di(methylphenyloximate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

acetophenone oxime (613-91-2) + triphenylantimony (603-36-1) → bis(phenylmethylketoximato)triphenylantimony(V) (474647-34-2,75392-03-9)

Guidance literature:

With (CH₃)3COOH; In benzene; byproducts: (CH3)3COH, H2O; addn. of a soln. of peroxide in benzene to a soln. of antimony compd. and ligand in benzene with stirring during 20 min, keeping at 20°C for 2 h; sepn. of ppt., washing with hexane, drying; elem. anal.;

DOI:10.1023/A:1019634307064

Reference yield: 88.0%

acetophenone oxime (613-91-2) + triphenylantimony dichloride (594-31-0,34716-91-1,20265-29-6) → bis(phenylmethylketoximato)triphenylantimony(V) (474647-34-2,75392-03-9)

Guidance literature:

With sodium; In benzene; byproducts: NaCl; reflux for about 2 h; NaCl was filtered off, filtrate was evapd. in vac., recrystd. by dissolving in benzene and keeping the whole soln. in the freezer for a night after addn. of light petroleum, dried in vac., elem. anal.;

Reference yield:

acetophenone oxime (613-91-2) + triphenylantimony (603-36-1) → O-triphenylantimony(V) di(methylphenyloximate) (474647-34-2,75392-03-9)

Guidance literature:

With H₂O₂; In diethyl ether; water; aq. soln. of H2O2 added to soln. of Sb(C6H5)3 and acetophenone oxime in ether, kept for 12 h at 293 K; filtered, dried; elem. anal.;

DOI:10.1134/S0036024411080218

upstream raw materials:

acetophenone oxime

triphenylantimony dichloride

triphenylantimony

triphenylantimony dibromide

Downstream raw materials:

triphenylantimony