IrHCl₂PC₆H₅(OCH₂CH₃)2(P(C₆H₅)3)2

Base Information

Chemical Name:IrHCl₂PC₆H₅(OCH₂CH₃)2(P(C₆H₅)3)2
CAS No.:273922-25-1
Molecular Formula:C₄₆H₄₆Cl₂IrO₂P₃
Molecular Weight:986.917
Hs Code.:

IrHCl<sub>2</sub>PC<sub>6</sub>H<sub>5</sub>(OCH<sub>2</sub>CH<sub>3</sub>)2(P(C<sub>6</sub>H<sub>5</sub>)3)2

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Suppliers and Price of IrHCl₂PC₆H₅(OCH₂CH₃)2(P(C₆H₅)3)2

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of IrHCl₂PC₆H₅(OCH₂CH₃)2(P(C₆H₅)3)2

Chemical Property:

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Technology Process of IrHCl₂PC₆H₅(OCH₂CH₃)2(P(C₆H₅)3)2

There total 2 articles about IrHCl₂PC₆H₅(OCH₂CH₃)2(P(C₆H₅)3)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 16971-01-0,24846-85-3,28060-70-0,77448-67-0
mer-IrHCl₂(PPh₃)3

: 1638-86-4
diethyl phenylphosphonite

: 273922-25-1
[IrHCl₂(PC₆H₅(OC₂H₅)2)(P(C₆H₅)3)2]

Guidance literature:: In benzene; under inert atm.; excess of phosphite was added to soln. of Ir-complex in benzene, heated under reflux for 2 h; solvent was removed under reduced pressure, triturated with EtOH, filtered off, crystd. from benzene/EtOH; elem. anal.;
DOI:10.1039/a909404k

Reference yield:

: 273922-32-0
IrCl₂(CH₃NHNH₂)(PC₆H₅(OC₂H₅)2)(P(C₆H₅)3)2⁽¹⁺⁾*B(C₆H₅)4^(1-)=[IrCl₂(CH₃NHNH₂)(PC₆H₅(OC₂H₅)2)(P(C₆H₅)3)2]B(C₆H₅)4

: 273922-25-1
[IrHCl₂(PC₆H₅(OC₂H₅)2)(P(C₆H₅)3)2]

Guidance literature:: With Pb(OAc)4; In dichloromethane; under inert atm.; Pb(OAc)4 was added in portions to the Ir complex in CH2Cl2 at -30°C, mixt. was brought to room temp.; filtered, solvent was removed under reduced pressure, triturated with EtOH with excess of NaBPh4, filtered off, crystd. from CH2Cl2/EtOH;
DOI:10.1039/a909404k

Reference yield: 70.0%

: 1013-88-3
Benzophenone imine

: 273922-25-1
IrHCl₂PC₆H₅(OCH₂CH₃)2(P(C₆H₅)3)2

: 143-66-8
sodium tetraphenyl borate

: 1021396-04-2
[IrHCl(η1-NH=CPh2)(PPh(OEt)2Ph)(PPh3)2][BPh4]

Guidance literature:: With triflic acid; In dichloromethane; inert atm., Me compd. in CH2Cl2 treated with excess ligand, stirred for 20 h, evapd., triturated with ethanolic soln. of excess NaBPh4; ppt. filtered off, recrystd. (CH2Cl2/ethanol), elem. anal.;
DOI:10.1016/j.ica.2006.12.001