(R)-1,1'-binaphthane-2,2'-diyl phenyl phosphite

Base Information

• Chemical Name: (R)-1,1'-binaphthane-2,2'-diyl phenyl phosphite
• CAS No.: 1247952-48-2
• Molecular Formula: C₂₆H₁₇O₃P
• Molecular Weight: 408.393
• Mol file: 1247952-48-2.mol

Synonyms:

Chemical Property of (R)-1,1'-binaphthane-2,2'-diyl phenyl phosphite

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (R)-1,1'-binaphthane-2,2'-diyl phenyl phosphite

There total 1 articles about (R)-1,1'-binaphthane-2,2'-diyl phenyl phosphite which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

binaphthol chlorophosphite (137156-22-0,171878-71-0,155613-52-8) + phenol (108-95-2,27073-41-2) → (Sa)-2-(phenoxy)-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine (188055-47-2,256441-54-0,1247952-48-2)

Guidance literature:

With triethylamine; In tetrahydrofuran; Combinatorial reaction / High throughput screening (HTS);

DOI:10.1021/om300194k

Reference yield: 81.0%

dichloro(benzene)ruthenium(II) dimer (37366-09-9) + (R)-1,1'-binaphthane-2,2'-diyl phenyl phosphite (1247952-48-2,188055-47-2,256441-54-0) → [RuCl2(η6-benzene)((R)-PhOP(binaphthoxy))] (1247628-76-7,1247628-93-8)

Guidance literature:

In CH₂Cl₂; (N2) Ru complex and ligand in CH2Cl2 were stirred at room temp. for 24 h; soln. was filtered and evapd. to dryness, residue was washed with Et2O-hexane (1:3) and vac.-dried;

DOI:10.1039/c0dt00140f

Reference yield: 79.0%

[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 (52462-29-0) + (R)-1,1'-binaphthane-2,2'-diyl phenyl phosphite (1247952-48-2,188055-47-2,256441-54-0) → [RuCl2(η6-p-cymene)((R)-PhOP(binaphthoxy))] (1247628-82-5,1247629-00-0)

Guidance literature:

In CH₂Cl₂; (N2) Ru complex and ligand in CH2Cl2 were stirred at room temp. for 1 h; soln. was filtered and evapd. to dryness, residue was washed with Et2O-hexane (1:3) and vac.-dried;

DOI:10.1039/c0dt00140f

upstream raw materials:

binaphthol chlorophosphite

phenol

Downstream raw materials:

[RuCl2(η6-benzene)((rac)-PhOP(binaphthoxy))]

[RuCl2(η6-p-cymene)(rac-PhOP(binaphthoxy))]

Rh(acac)((S)-binaphthyl phenyl phosphite)PPh₃

cis-[PtCl₂((R)-1,1'-binaphthane-2,2'-diyl phenyl phosphite)2]