1,2-Dichloro-3-pentylbenzene

Base Information

• Chemical Name: 1,2-Dichloro-3-pentylbenzene
• CAS No.: 171291-81-9
• Molecular Formula: C₁₁H₁₄Cl₂
• Molecular Weight: 217.138
• Mol file: 171291-81-9.mol

Synonyms:

Chemical Property of 1,2-Dichloro-3-pentylbenzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,2-Dichloro-3-pentylbenzene

There total 3 articles about 1,2-Dichloro-3-pentylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,2-Dichloro-3-((Z)-pent-1-enyl)-benzene → 1,2-Dichloro-3-pentylbenzene (171291-81-9)

Guidance literature:

With hydrogen; platinum(IV) oxide; In ethanol; for 4h; Yield given; Ambient temperature;

DOI:10.1080/10587259508038694

Reference yield:

Hexanoyl chloride (142-61-0) → C11H14Cl2 + 1,2-Dichloro-3-pentylbenzene (171291-81-9)

Guidance literature:

Multi-step reaction with 2 steps

1: pyridine; dihydrogen peroxide / diethyl ether / 2 h / -10 - 0 °C / Inert atmosphere

2: iron(III) paratoluenesulfonate / 8 h / 100 °C / Schlenk technique; Inert atmosphere

With pyridine; iron(III) paratoluenesulfonate; dihydrogen peroxide; In diethyl ether;

DOI:10.1021/acs.orglett.7b03244

Reference yield:

dihexanoyl peroxide (2400-59-1) + 1,2-dichloro-benzene (95-50-1) → C11H14Cl2 + 1,2-Dichloro-3-pentylbenzene (171291-81-9)

Guidance literature:

With iron(III) paratoluenesulfonate; at 100 ℃; for 8h; Overall yield = 56 %; Overall yield = 60 mg; regioselective reaction; Schlenk technique; Inert atmosphere;

DOI:10.1021/acs.orglett.7b03244

upstream raw materials:

Hexanoyl chloride

dihexanoyl peroxide

1,2-dichloro-benzene