tris(4-aminophenyl)methylium Ni(2-thioxo-1,3-dithiole-4,5-dithiolato)2

Base Information

• Chemical Name: tris(4-aminophenyl)methylium Ni(2-thioxo-1,3-dithiole-4,5-dithiolato)2
• CAS No.: 910138-03-3
• Molecular Formula: C₆NiS₁₀*C₁₉H₁₈N₃
• Molecular Weight: 739.788
• Mol file: 910138-03-3.mol

Synonyms:

Chemical Property of tris(4-aminophenyl)methylium Ni(2-thioxo-1,3-dithiole-4,5-dithiolato)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tris(4-aminophenyl)methylium Ni(2-thioxo-1,3-dithiole-4,5-dithiolato)2

There total 1 articles about tris(4-aminophenyl)methylium Ni(2-thioxo-1,3-dithiole-4,5-dithiolato)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 34.0%

nickel(II) chloride hexahydrate + 4,5-bis(benzoylthio)-1,3-dithiole-2-thione (68494-08-6) + basic red 9 (569-61-9,131883-55-1,187112-40-9) → tris(4-aminophenyl)methylium Ni(2-thioxo-1,3-dithiole-4,5-dithiolato)2 (910138-03-3)

Guidance literature:

With sodium methoxide; I₂; NaI; In methanol; addn. of MeONa in methanol to a suspn. of ligand in methanol at room temp. over 20 min, addn. of nickel salt, addn. of i2 and NaI after 10 min, addn. of a soln. of chloride salt in methanol after 10 min, stirring for30 min; cooling in refrigerator overnight, dissolving ppt. in hot acetonitrile/benzene mixt., filtration, standing for 1 d for crystn.; elem. anal.;

DOI:10.1246/bcsj.79.1060

upstream raw materials:

4,5-bis(benzoylthio)-1,3-dithiole-2-thione

basic red 9