Ir(PPh₃)2(CO)(3,5-dimethylpyrazolate)cis-dihydride

Base Information

Chemical Name:Ir(PPh₃)2(CO)(3,5-dimethylpyrazolate)cis-dihydride
CAS No.:91320-12-6
Molecular Formula:C₄₂H₃₉IrN₂OP₂
Molecular Weight:841.952
Hs Code.:

Ir(PPh<sub>3</sub>)2(CO)(3,5-dimethylpyrazolate)cis-dihydride

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Chemical Property of Ir(PPh₃)2(CO)(3,5-dimethylpyrazolate)cis-dihydride

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Technology Process of Ir(PPh₃)2(CO)(3,5-dimethylpyrazolate)cis-dihydride

There total 1 articles about Ir(PPh₃)2(CO)(3,5-dimethylpyrazolate)cis-dihydride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 89340-57-8
trans-Ir(PPh₃)2(CO)(3,5-dimethylpyrazolate)

: 91320-12-6
Ir(PPh₃)2(CO)(3,5-dimethylpyrazolate)cis-dihydride

Guidance literature:: With H₂; In benzene; H2 was bubbled for 2 d.; addn. of n-pentane, concd., The pp. was washed with benzene. recrystn.(benzene/n-pentane);
DOI:10.1016/0022-328X(84)80280-6

Reference yield: 54.0%

: 67969-82-8
tetrafluoroboric acid diethyl ether

: 91320-12-6
Ir(PPh₃)2(CO)(3,5-dimethylpyrazolate)cis-dihydride

: Ir(triphenylphosphine)2(CO)(H)2(3,5-dimethylpyrazole-N)BF₄*Et₂O

: Ir(triphenylphosphine)2(CO)(H)2(3,5-dimethylpyrazole-N)BF₄*benzene

Guidance literature:: With benzene; In benzene; under N2, addn. of HBF4*Et2O to stirred soln. of Ir complex in benzene, stirred for 1h; suspension evapn. to dryness, washed (benzene), redissolved (CH2Cl2), filtered, concd., addn. of Et2O, pptn., elem. anal., concn. of benzene extract yield the other conformer;

Reference yield: 46.0%

: 91320-12-6
Ir(PPh₃)2(CO)(3,5-dimethylpyrazolate)cis-dihydride

: 13453-07-1
gold(III) chloride

: 107453-18-9
Ir(triphenylphosphine)2(CO)(H)2(3,5-dimethylpyrazol-N){AuCl₄}

Guidance literature:: In dichloromethane; soln. of AuCl3 was added to stirred soln. of Ir complex at room temp.; concd., filtered, addn. of large amt. of Et2O, pptn., crystn. (CH2Cl2/Et2O), elem. anal.;