Pd((NC₄H₈O)C₆H₄P(C₁₀H₁₅)2)(NH₃)(C₆H₄C₂C₆H₅)⁽¹⁺⁾*CF₃SO₃^(1-)=Pd((NC₄H₈O)C₆H₄P(C₁₀H₁₅)2)(NH₃)(C₆H₄C₂C₆H₅)CF₃SO₃

Base Information

• Chemical Name: Pd((NC₄H₈O)C₆H₄P(C₁₀H₁₅)2)(NH₃)(C₆H₄C₂C₆H₅)⁽¹⁺⁾*CF₃SO₃^(1-)=Pd((NC₄H₈O)C₆H₄P(C₁₀H₁₅)2)(NH₃)(C₆H₄C₂C₆H₅)CF₃SO₃
• CAS No.: 1355198-36-5
• Molecular Formula: CF₃O₃S*C₄₄H₅₄N₂OPPd
• Molecular Weight: 913.39
• Mol file: 1355198-36-5.mol

Synonyms:

Chemical Property of Pd((NC₄H₈O)C₆H₄P(C₁₀H₁₅)2)(NH₃)(C₆H₄C₂C₆H₅)⁽¹⁺⁾*CF₃SO₃^(1-)=Pd((NC₄H₈O)C₆H₄P(C₁₀H₁₅)2)(NH₃)(C₆H₄C₂C₆H₅)CF₃SO₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Pd((NC₄H₈O)C₆H₄P(C₁₀H₁₅)2)(NH₃)(C₆H₄C₂C₆H₅)⁽¹⁺⁾*CF₃SO₃^(1-)=Pd((NC₄H₈O)C₆H₄P(C₁₀H₁₅)2)(NH₃)(C₆H₄C₂C₆H₅)CF₃SO₃

There total 2 articles about Pd((NC₄H₈O)C₆H₄P(C₁₀H₁₅)2)(NH₃)(C₆H₄C₂C₆H₅)⁽¹⁺⁾*CF₃SO₃^(1-)=Pd((NC₄H₈O)C₆H₄P(C₁₀H₁₅)2)(NH₃)(C₆H₄C₂C₆H₅)CF₃SO₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Pd((NC4H8O)C6H4P(C10H15)2)(C6H4C2C6H5)(1+)*CF3SO3(1-)=Pd((NC4H8O)C6H4P(C10H15)2)(C6H4C2C6H5)CF3SO3 (1355198-38-7) + ammonia (7664-41-7) → Pd((NC4H8O)C6H4P(C10H15)2)(NH3)(C6H4C2C6H5)(1+)*CF3SO3(1-)=Pd((NC4H8O)C6H4P(C10H15)2)(NH3)(C6H4C2C6H5)CF3SO3 (1355198-36-5)

Guidance literature:

In chloroform-d1; treatment with 3 equiv of NH3; detected by NMR spectra;

DOI:10.1021/om201122q

Reference yield:

Pd((NC4H8O)C6H4P(C10H15)2)Br(C6H4C2C6H5) (1355198-34-3) + ammonia (7664-41-7) + silver trifluoromethanesulfonate (2923-28-6) → Pd((NC4H8O)C6H4P(C10H15)2)(NH3)(C6H4C2C6H5)(1+)*CF3SO3(1-)=Pd((NC4H8O)C6H4P(C10H15)2)(NH3)(C6H4C2C6H5)CF3SO3 (1355198-36-5)

Guidance literature:

In 1,4-dioxane; dichloromethane; (N2, glovebox) NH3 in dioxane was added to a soln. of complex in CH2Cl2,the soln. was stirred briefly, replaced into the glovebox, AgSO3CF3 was added, closed, stirred for 1 h at room temp.; ppt. was filtered, the filtrate was triturated with pentane (2x), concd.;

DOI:10.1021/om201122q

Reference yield: 83.0%

Pd((NC4H8O)C6H4P(C10H15)2)(NH3)(C6H4C2C6H5)(1+)*CF3SO3(1-)=Pd((NC4H8O)C6H4P(C10H15)2)(NH3)(C6H4C2C6H5)CF3SO3 (1355198-36-5) + silver trifluoromethanesulfonate (2923-28-6) → Pd((NC4H8O)C6H4P(C10H15)2)(C6H4C2C6H5)(1+)*CF3SO3(1-)=Pd((NC4H8O)C6H4P(C10H15)2)(C6H4C2C6H5)CF3SO3 (1355198-38-7)

Guidance literature:

In neat (no solvent); byproducts: NH3; expose to vac.; filtered, concd., dried in vac.; elem. anal.;

DOI:10.1021/om201122q

upstream raw materials:

Pd((NC₄H₈O)C₆H₄P(C₁₀H₁₅)2)Br(C₆H₄C₂C₆H₅)

ammonia

silver trifluoromethanesulfonate

Pd((NC₄H₈O)C₆H₄P(C₁₀H₁₅)2)(C₆H₄C₂C₆H₅)⁽¹⁺⁾*CF₃SO₃^(1-)=Pd((NC₄H₈O)C₆H₄P(C₁₀H₁₅)2)(C₆H₄C₂C₆H₅)CF₃SO₃

Downstream raw materials:

Pd((NC₄H₈O)C₆H₄P(C₁₀H₁₅)2)(C₆H₄C₂C₆H₅)⁽¹⁺⁾*CF₃SO₃^(1-)=Pd((NC₄H₈O)C₆H₄P(C₁₀H₁₅)2)(C₆H₄C₂C₆H₅)CF₃SO₃