Benzyl 2-O-<α-Ethoxy-α-(trifluoromethyl)phenylacetyl>-β-L-oleandroside

Base Information

Chemical Name:Benzyl 2-O-<α-Ethoxy-α-(trifluoromethyl)phenylacetyl>-β-L-oleandroside
CAS No.:86972-13-6
Molecular Formula:C₂₄H₂₇F₃O₆
Molecular Weight:468.47
Hs Code.:

Synonyms:

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Chemical Property of Benzyl 2-O-<α-Ethoxy-α-(trifluoromethyl)phenylacetyl>-β-L-oleandroside

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Technology Process of Benzyl 2-O-<α-Ethoxy-α-(trifluoromethyl)phenylacetyl>-β-L-oleandroside

There total 6 articles about Benzyl 2-O-<α-Ethoxy-α-(trifluoromethyl)phenylacetyl>-β-L-oleandroside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 86972-06-7
(3S,4S,5S)-4,5-Bis(benzyloxy)-3-methoxyhexanal

: 86972-13-6
Benzyl 2-O-<α-Ethoxy-α-(trifluoromethyl)phenylacetyl>-β-L-oleandroside

Guidance literature:: Multi-step reaction with 3 steps

1: 85 percent / H₂ / Pd(OH)2/C / tetrahydrofuran / 20 h / 760 Torr

2: gas. HCl / 0.25 h

3: 10 mg / pyridine / CCl₄ / 12 h / Ambient temperature

With pyridine; hydrogenchloride; hydrogen; palladium dihydroxide; In tetrahydrofuran; tetrachloromethane;
DOI:10.1021/jo00168a022

Reference yield:

: 86972-04-5
(3S,4S,5S)-4,5-Bis(benzyloxy)-3-methoxyhexanol

: 86972-13-6
Benzyl 2-O-<α-Ethoxy-α-(trifluoromethyl)phenylacetyl>-β-L-oleandroside

Guidance literature:: Multi-step reaction with 4 steps

1: 77 percent / pyridinium chlorochromate (PCC), NaOAc, celite / CH₂Cl₂ / 3 h

2: 85 percent / H₂ / Pd(OH)2/C / tetrahydrofuran / 20 h / 760 Torr

3: gas. HCl / 0.25 h

4: 10 mg / pyridine / CCl₄ / 12 h / Ambient temperature

With pyridine; hydrogenchloride; Celite; hydrogen; sodium acetate; pyridinium chlorochromate; palladium dihydroxide; In tetrahydrofuran; tetrachloromethane; dichloromethane;
DOI:10.1021/jo00168a022

Reference yield:

: 86972-03-4
(3S,4S,5S)-4,5-Bis(benzyloxy)-3-methoxy-1-hexene

: 86972-13-6
Benzyl 2-O-<α-Ethoxy-α-(trifluoromethyl)phenylacetyl>-β-L-oleandroside

Guidance literature:: Multi-step reaction with 5 steps

1: 34 percent / 1) 9-BBN, 2) 30percent H₂O₂ / tetrahydrofuran / 1) 50 degC, 3 d, 2) 1 h

2: 77 percent / pyridinium chlorochromate (PCC), NaOAc, celite / CH₂Cl₂ / 3 h

3: 85 percent / H₂ / Pd(OH)2/C / tetrahydrofuran / 20 h / 760 Torr

4: gas. HCl / 0.25 h

5: 10 mg / pyridine / CCl₄ / 12 h / Ambient temperature

With pyridine; hydrogenchloride; 9-borabicyclo[3.3.1]nonane dimer; Celite; hydrogen; dihydrogen peroxide; sodium acetate; pyridinium chlorochromate; palladium dihydroxide; In tetrahydrofuran; tetrachloromethane; dichloromethane;
DOI:10.1021/jo00168a022