34-<3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl>-36,38-dimethoxy-4,14-dimethyl-1,7,11,17,21,29-hexaazaheptacyclo-<27.3.1.1^2,6.1^7,11.1^12,16.1^17,21.1^23,27>octatriaconta-2,4,6-(38),12,14,16(36),23,25,27(34)-nonaene-33,35,37-trione

Base Information

• Chemical Name: 34-<3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl>-36,38-dimethoxy-4,14-dimethyl-1,7,11,17,21,29-hexaazaheptacyclo-<27.3.1.1^2,6.1^7,11.1^12,16.1^17,21.1^23,27>octatriaconta-2,4,6-(38),12,14,16(36),23,25,27(34)-nonaene-33,35,37-trione
• CAS No.: 104463-69-6
• Molecular Formula: C₅₁H₆₄N₆O₆
• Molecular Weight: 857.106

Synonyms:

Chemical Property of 34-<3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl>-36,38-dimethoxy-4,14-dimethyl-1,7,11,17,21,29-hexaazaheptacyclo-<27.3.1.1^2,6.1^7,11.1^12,16.1^17,21.1^23,27>octatriaconta-2,4,6-(38),12,14,16(36),23,25,27(34)-nonaene-33,35,37-trione

Chemical Property:

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Technology Process of 34-<3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl>-36,38-dimethoxy-4,14-dimethyl-1,7,11,17,21,29-hexaazaheptacyclo-<27.3.1.1^2,6.1^7,11.1^12,16.1^17,21.1^23,27>octatriaconta-2,4,6-(38),12,14,16(36),23,25,27(34)-nonaene-33,35,37-trione

There total 3 articles about 34-<3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl>-36,38-dimethoxy-4,14-dimethyl-1,7,11,17,21,29-hexaazaheptacyclo-<27.3.1.1^2,6.1^7,11.1^12,16.1^17,21.1^23,27>octatriaconta-2,4,6-(38),12,14,16(36),23,25,27(34)-nonaene-33,35,37-trione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-bromo-2,6-di-tert-butylanisole (1516-96-7) → 34-<3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl>-36,38-dimethoxy-4,14-dimethyl-1,7,11,17,21,29-hexaazaheptacyclo-<27.3.1.12,6.17,11.112,16.117,21.123,27>octatriaconta-2,4,6-(38),12,14,16(36),23,25,27(34)-nonaene-33,35,37-trione (104463-69-6)

Guidance literature:

Multi-step reaction with 3 steps

1: 1.) Mg, 2.) Ni(acac)2 / 1.) Et₂O, 2 h, reflux, 2.) Et₂O, 2 h, reflux

2: 44 percent / NBS, AIBN / CCl₄ / 1 h / Heating

3: 1.) NaH / 1.) THF, reflux, 20 h, 2.) THF, from -78 deg C to 25 deg C, 15 h

With bis(acetylacetonate)nickel(II); N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile); sodium hydride; magnesium; In tetrachloromethane;

DOI:10.1021/jo00373a001

Reference yield:

4'-methoxy-2,6-dimethyl-3',5'-bis(1,1-dimethylethyl)-1,1'-biphenyl (104463-76-5) → 34-<3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl>-36,38-dimethoxy-4,14-dimethyl-1,7,11,17,21,29-hexaazaheptacyclo-<27.3.1.12,6.17,11.112,16.117,21.123,27>octatriaconta-2,4,6-(38),12,14,16(36),23,25,27(34)-nonaene-33,35,37-trione (104463-69-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 44 percent / NBS, AIBN / CCl₄ / 1 h / Heating

2: 1.) NaH / 1.) THF, reflux, 20 h, 2.) THF, from -78 deg C to 25 deg C, 15 h

With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile); sodium hydride; In tetrachloromethane;

DOI:10.1021/jo00373a001

Reference yield:

1,3-bis<2-methoxy-3-(1-tetrahydro-(3H)-pyrimidinonyl)-5-methylphenyl>tetrahydro-2(1H)-pyrimidinone (83604-32-4) + 2,6-bis(bromomethyl)-3',5'-bis(1,1-dimethylethyl)-4'-methoxy-1,1'-biphenyl (104463-74-3) → 34-<3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl>-36,38-dimethoxy-4,14-dimethyl-1,7,11,17,21,29-hexaazaheptacyclo-<27.3.1.12,6.17,11.112,16.117,21.123,27>octatriaconta-2,4,6-(38),12,14,16(36),23,25,27(34)-nonaene-33,35,37-trione (104463-69-6)

Guidance literature:

With sodium hydride; Yield given. Multistep reaction; 1.) THF, reflux, 20 h, 2.) THF, from -78 deg C to 25 deg C, 15 h;

DOI:10.1021/jo00373a001

upstream raw materials:

1,3-bis<2-methoxy-3-(1-tetrahydro-(3H)-pyrimidinonyl)-5-methylphenyl>tetrahydro-2(1H)-pyrimidinone

2,6-bis(bromomethyl)-3',5'-bis(1,1-dimethylethyl)-4'-methoxy-1,1'-biphenyl

4-bromo-2,6-di-tert-butylanisole

4'-methoxy-2,6-dimethyl-3',5'-bis(1,1-dimethylethyl)-1,1'-biphenyl

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