Ru(2,6-bis(3-isoquinolyl)-(4-tolyl)pyridine)Cl₃

Base Information

Chemical Name:Ru(2,6-bis(3-isoquinolyl)-(4-tolyl)pyridine)Cl₃
CAS No.:259251-60-0
Molecular Formula:C₃₀H₂₁Cl₃N₃Ru
Molecular Weight:630.946
Hs Code.:

Ru(2,6-bis(3-isoquinolyl)-(4-tolyl)pyridine)Cl<sub>3</sub>

Synonyms:

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Chemical Property of Ru(2,6-bis(3-isoquinolyl)-(4-tolyl)pyridine)Cl₃

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Technology Process of Ru(2,6-bis(3-isoquinolyl)-(4-tolyl)pyridine)Cl₃

There total 1 articles about Ru(2,6-bis(3-isoquinolyl)-(4-tolyl)pyridine)Cl₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 14898-67-0
ruthenium(III) chloride trihydrate

: 259251-58-6
2,6-bis(3-isoquinolyl)-4-(p-tolyl)pyridine

: 259251-60-0
Ru(2,6-bis(3-isoquinolyl)-(4-tolyl)pyridine)Cl₃

Guidance literature:: In ethanol; to abs. EtOH were added RuCl3*3H2O and ligand, mixt. heated at reflux for 3 h with vigorous stirring, mixt. was cooled to room temp.; ppt. was collected by vac. filtration, washed with abs. EtOH, followed by Et2O, dried under vac.;
DOI:10.1002/(sici)1099-0682(200001)2000:1<113::aid-ejic113>3.0.co;2-9

Reference yield: 64.0%

: 17084-13-8
potassium hexafluorophosphate

: 259251-60-0
Ru(2,6-bis(3-isoquinolyl)-(4-tolyl)pyridine)Cl₃

: 116287-98-0
2,9-bis-(4-methylphenyl)-1,10-phenanthroline

: 259251-57-5
(2,6-bis(3-isoquinolyl)-(4-tolyl)pyridine)(2,9-bis(p-tolyl)-1,10-phenanthroline)ruthenium(II) hexafluorophosphate

Guidance literature:: With N-ethylmorpholine; In water; acetic acid; suspn. of Ru-complex and ligand in glacial acetic acid with 2-3 drops ofN-ethylmorpholine was refluxed under Ar for 3 h; solvent removed under reduced pressure, solid redissolved in MeOH, filtered, aq. soln. of KPF6 was added, silica gel chromy., eluted with CH2Cl2/CH3OH; elem. anal.;
DOI:10.1002/(sici)1099-0682(200001)2000:1<113::aid-ejic113>3.0.co;2-9

Reference yield: 49.0%

: 17084-13-8
potassium hexafluorophosphate

: 259251-60-0
Ru(2,6-bis(3-isoquinolyl)-(4-tolyl)pyridine)Cl₃

: 201403-32-9
2-(p-methoxyphenyl)-9-(5'-methylpyridin-2'-yl)-1,10-phenanthroline

: (2,6-bis(3-isoquinolyl)-(4-tolyl)pyridine)(2-p-anisyl-9-(4-methyl-2-pyridyl)-1,10-phenanthroline)ruthenium(II) dihexafluorophosphate

Guidance literature:: With N-ethylmorpholine; In water; acetic acid; suspn. of Ru-complex and ligand in glacial acetic acid with 2-3 drops ofN-ethylmorpholine was refluxed under Ar for 5 h; solvent removed under reduced pressure, solid redissolved in MeOH, filtered, aq. soln. of KPF6 was added, silica gel chromy., eluted with CH2Cl2/CH3OH; elem. anal.;
DOI:10.1002/(sici)1099-0682(200001)2000:1<113::aid-ejic113>3.0.co;2-9