[(Z)-4-(2-Bromo-1-butoxy-ethoxy)-but-2-enylsulfanyl]-benzene

Base Information

• Chemical Name: [(Z)-4-(2-Bromo-1-butoxy-ethoxy)-but-2-enylsulfanyl]-benzene
• CAS No.: 110969-15-8
• Molecular Formula: C₁₆H₂₃BrO₂S
• Molecular Weight: 359.327
• Mol file: 110969-15-8.mol

Synonyms:

Chemical Property of [(Z)-4-(2-Bromo-1-butoxy-ethoxy)-but-2-enylsulfanyl]-benzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(Z)-4-(2-Bromo-1-butoxy-ethoxy)-but-2-enylsulfanyl]-benzene

There total 1 articles about [(Z)-4-(2-Bromo-1-butoxy-ethoxy)-but-2-enylsulfanyl]-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

-butyl vinyl ether (111-34-2,92680-80-3) + cis-4-phenylthiobut-2-en-1-ol (110969-14-7) → bromoacetaldehyde 4-phenylthiobut-2-enyl butyl acetal (82918-73-8,110969-15-8)

Guidance literature:

With N-Bromosuccinimide; at -50 - -20 ℃;

Reference yield:

[(Z)-4-(2-Bromo-1-butoxy-ethoxy)-but-2-enylsulfanyl]-benzene (110969-15-8) → 3-vinylbutyrolactone (53627-36-4,107022-86-6,107080-45-5,121959-61-3)

Guidance literature:

Multi-step reaction with 2 steps

1: 91 percent / sodium tetrahydroborate / polymer-supported organotin / benzene; ethanol / 0.5 h / Irradiation

2: 95 percent / Jones reagent / acetone

With sodium tetrahydroborate; jones reagent; polymer-supported organotin; In ethanol; acetone; benzene;

DOI:10.1021/ja00384a082

Reference yield:

bromoacetaldehyde 4-phenylthiobut-2-enyl butyl acetal (82918-73-8,110969-15-8) → 3-vinylbutyrolactone (53627-36-4,107022-86-6,107080-45-5,121959-61-3)

Guidance literature:

Multi-step reaction with 2 steps

1: 91 percent / NaBH₄, polymeric tin compound / ethanol; benzene / 2 h / Ambient temperature; Irradiation

2: 95 percent / Jones reagent / acetone

With sodium tetrahydroborate; jones reagent; polymeric tin compound; In ethanol; acetone; benzene;

upstream raw materials:

-butyl vinyl ether

cis-4-phenylthiobut-2-en-1-ol

Downstream raw materials:

3-vinylbutyrolactone