6,6-dichloro-1-methyl-4-phenyl-4-phosphabicyclo[3.1.0]hexane-dichloromethylborane

Base Information

• Chemical Name: 6,6-dichloro-1-methyl-4-phenyl-4-phosphabicyclo[3.1.0]hexane-dichloromethylborane
• CAS No.: 179989-96-9
• Molecular Formula: C₁₃H₁₆BCl₄P
• Molecular Weight: 355.867
• Mol file: 179989-96-9.mol

Synonyms:

Chemical Property of 6,6-dichloro-1-methyl-4-phenyl-4-phosphabicyclo[3.1.0]hexane-dichloromethylborane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 6,6-dichloro-1-methyl-4-phenyl-4-phosphabicyclo[3.1.0]hexane-dichloromethylborane

There total 2 articles about 6,6-dichloro-1-methyl-4-phenyl-4-phosphabicyclo[3.1.0]hexane-dichloromethylborane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 33.0%

chloroform (67-66-3,8013-54-5) + 4-methyl-1-phenyl-2,3-dihydro-1H-phosphol-1-ane borane (179989-93-6) + sodium trichloroacetate (650-51-1) → 4-methyl-1-phenyl-2,3-dihydro-1H-phosphole-dichloromethylborane (179989-94-7) + 6,6-dichloro-1-methyl-4-phenyl-4-phosphabicyclo[3.1.0]hexane-dichloromethylborane (179989-96-9)

Guidance literature:

With N-benzyl-N,N,N-triethylammonium chloride; In chloroform; refluxing borane with NaO2CCl3 and triethylbenzylammonium chloride for 48 h; filtration, evapn., repeated chromy. (SiO2, MeOH/CHCl3);

DOI:10.1016/0022-328X(96)06134-7

Reference yield:

4-methyl-1-phenyl-2,3-dihydro-1H-phosphol-1-ane borane (179989-93-6) → 4-methyl-1-phenyl-2,3-dihydro-1H-phosphole-dichloromethylborane (179989-94-7) + 6,6-dichloro-1-methyl-4-phenyl-4-phosphabicyclo[3.1.0]hexane-dichloromethylborane (179989-96-9)

Guidance literature:

With dichloromethane;

DOI:10.1080/10426509608545189

upstream raw materials:

chloroform

4-methyl-1-phenyl-2,3-dihydro-1H-phosphol-1-ane borane

sodium trichloroacetate