1E,3-butadiene, [2-isopropyl-5-methylcyclohexyloxy(1R,2S,5R)]ether

Base Information

Chemical Name:1E,3-butadiene, [2-isopropyl-5-methylcyclohexyloxy(1R,2S,5R)]ether
CAS No.:250267-04-0
Molecular Formula:C₁₄H₂₄O
Molecular Weight:208.344
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1E,3-butadiene, [2-isopropyl-5-methylcyclohexyloxy(1R,2S,5R)]ether

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Technology Process of 1E,3-butadiene, [2-isopropyl-5-methylcyclohexyloxy(1R,2S,5R)]ether

There total 15 articles about 1E,3-butadiene, [2-isopropyl-5-methylcyclohexyloxy(1R,2S,5R)]ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

: 19493-09-5
Methylenetriphenylphosphorane

: 250267-02-8
3-[2-isopropyl-5-methylcyclohexyloxy(1R,2S,5R)]-2E-propenal

: 250267-04-0
1E,3-butadiene, [2-isopropyl-5-methylcyclohexyloxy(1R,2S,5R)]ether

Guidance literature:: In tetrahydrofuran; hexane; at -78 - 20 ℃; for 0.5h;
DOI:10.1016/S0040-4020(99)00666-3

Reference yield:

: 108167-50-6
ethynyl, [2-isopropyl-5-methylcyclohexyl(1R,2S,5R)]ether

: 250267-04-0
1E,3-butadiene, [2-isopropyl-5-methylcyclohexyloxy(1R,2S,5R)]ether

Guidance literature:: Multi-step reaction with 4 steps

1: 57 percent / tetrakis(triphenylphosphine)palladium; copper(I) iodide; isopropylamine

2: 52 percent / H₂; Ni(OAc)2; sodium borohydride, ethylenediamine / ethanol / 1 h

3: 99 percent / tetraphenylporphyrin; ¹O₂ / CH₂Cl₂ / 0.17 h / 0 °C / Irradiation

4: 64 percent / tetrahydrofuran; hexane / 0.5 h / -78 - 20 °C

With sodium tetrahydroborate; copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; hydrogen; oxygen; nickel diacetate; 5,15,10,20-tetraphenylporphyrin; isopropylamine; ethylenediamine; In tetrahydrofuran; ethanol; hexane; dichloromethane; 1: Substitution / 2: Hydrogenation / 3: Oxidation / 4: Condensation;
DOI:10.1016/S0040-4020(99)00666-3

Reference yield:

: 2216-51-5
(-)-menthol

: 250267-04-0
1E,3-butadiene, [2-isopropyl-5-methylcyclohexyloxy(1R,2S,5R)]ether

Guidance literature:: Multi-step reaction with 4 steps

1: 54 percent / Et₃N / diethyl ether / 15 h

2: 73 percent / DIBAL / diethyl ether; hexane / -78 °C

3: 100 percent / N-methylmorpholine N-oxide; tetra-n-propylammonium perruthenate / CH₂Cl₂ / 0.75 h / 20 °C

4: 64 percent / tetrahydrofuran; hexane / 0.5 h / -78 - 20 °C

With tetrapropylammonium perruthennate; diisobutylaluminium hydride; 4-methylmorpholine N-oxide; triethylamine; In tetrahydrofuran; diethyl ether; hexane; dichloromethane; 1: Addition / 2: Reduction / 3: Oxidation / 4: Condensation;
DOI:10.1016/S0040-4020(99)00666-3