Ru(4'-(3,5-bis(tert-butyl)phenyl)-2,2':6',2''-terpyridine)Cl₃

Base Information

Chemical Name:Ru(4'-(3,5-bis(tert-butyl)phenyl)-2,2':6',2''-terpyridine)Cl₃
CAS No.:660860-77-5
Molecular Formula:C₂₉H₃₁Cl₃N₃Ru
Molecular Weight:629.014
Hs Code.:

Ru(4'-(3,5-bis(tert-butyl)phenyl)-2,2':6',2''-terpyridine)Cl<sub>3</sub>

Synonyms:

Suppliers and Price of Ru(4'-(3,5-bis(tert-butyl)phenyl)-2,2':6',2''-terpyridine)Cl₃

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of Ru(4'-(3,5-bis(tert-butyl)phenyl)-2,2':6',2''-terpyridine)Cl₃

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

Safty Information:

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Technology Process of Ru(4'-(3,5-bis(tert-butyl)phenyl)-2,2':6',2''-terpyridine)Cl₃

There total 1 articles about Ru(4'-(3,5-bis(tert-butyl)phenyl)-2,2':6',2''-terpyridine)Cl₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.5%

: 14898-67-0
ruthenium(III) chloride trihydrate

: 227948-34-7
4'-(3,5-di-tert-butylphenyl)-2,2':6',2-terpyridine

: 660860-77-5
Ru(4'-(3,5-bis(tert-butyl)phenyl)-2,2':6',2''-terpyridine)Cl₃

Guidance literature:: In ethanol; 4-(3,5-di-tert-butyl)phenyl-2,2':6',2''-terpyridine and one equiv. of RuCl3*3H2O dissolved in EtOH; soln. heated to reflux for 1 h; cooled; ppt. filtered; solid washed (EtOH, H2O, Et2O); dried (air);
DOI:10.1039/b310198c

Reference yield: 62.0%

: 17084-13-8
potassium hexafluorophosphate

: 660860-77-5
Ru(4'-(3,5-bis(tert-butyl)phenyl)-2,2':6',2''-terpyridine)Cl₃

: 5144-89-8
1,10-phenanthroline hydrate

: lithium chloride

: 660860-66-2
[RuCl(4-(3,5-di-tert-butyl)phenyl-2,2':6',2''-terpyridine)(1,10-phenathroline)][PF₆]

Guidance literature:: With triethylamine; In ethanol; water; Ru complex, monoaqua-1,10-phenanthroline, LiCl, Et3N heated to reflux inEtOH-H2O for 4 h under Ar; soln. of satd. aq. KPF6 added; EtOH evapd.; ppt. filtered; washed (H2O, ether); column chromd. on SiO2 (Me2CO-H2O-satd. KNO3 (aq.), 100:5:0.1 as eluent); Et2O diffused into acetone soln.;
DOI:10.1039/b310198c

Reference yield:

: 17084-13-8
potassium hexafluorophosphate

: 660860-77-5
Ru(4'-(3,5-bis(tert-butyl)phenyl)-2,2':6',2''-terpyridine)Cl₃

: 888940-08-7
N₂C₁₂H₆(C₆H₄O(CH₂CH₂O)3C₆H₄CN)(C₆H₄O(CH₂CH₂O)3CH₂CH₂SOCH₃)

: 888940-16-7,889103-60-0
(RuCl(C₁₄H₂₁C₁₅H₁₀N₃)(N₂C₃₆H₃₈O₈(C₆H₄CN)(C₂H₄SOCH₃)))⁽¹⁺⁾*PF₆^(1-)=[RuCl(C₂₉H₃₁N₃)(N₂C₃₆H₃₈O₈(C₆H₄CN)(C₂H₄SOCH₃))]PF₆

Guidance literature:: With lithium chloride; In ethanol; water; under Ar; hot soln. of phenanthroline derivative in EtOH added to suspn.Ru complex and LiCl in aq. EtOH, mixt. heated at reflux for 5 h, aq. KP F6 added to cooled soln.; EtOH evapd. under vac., ppt. filtered off, washed with water, solid recovered with acetone and evapd. to dryness, chromy. (silica, acetone/water/satd. KNO3 (300/15/2); isomers not separated;
DOI:10.1021/ic060029p