bis(triphenylphosphine)bis(phenalenone)copper tetrafluoroborate

Base Information

• Chemical Name: bis(triphenylphosphine)bis(phenalenone)copper tetrafluoroborate
• CAS No.: 189205-29-6
• Molecular Formula: BF₄*C₆₂H₄₆CuO₂P₂
• Molecular Weight: 1035.34
• Mol file: 189205-29-6.mol

Synonyms:

Chemical Property of bis(triphenylphosphine)bis(phenalenone)copper tetrafluoroborate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis(triphenylphosphine)bis(phenalenone)copper tetrafluoroborate

There total 1 articles about bis(triphenylphosphine)bis(phenalenone)copper tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

silver tetrafluoroborate (14104-20-2) + bis(triphenylphosphine)copper(I) chloride (25577-10-0,20279-88-3) + Perinaphthenon (548-39-0) → bis(triphenylphosphine)bis(phenalenone)copper tetrafluoroborate (189205-29-6)

Guidance literature:

In dichloromethane; N2-atmosphere; stirring Cu-complex with 1 equiv. AgBF4 at room temp. for30 min, filtration, addn. of 2 equiv. ketone, stirring at 40°C f or 30 min; cooling to room temp., filtration, hexane addn. (pptn.), collection, washing (ether); elem. anal.;

DOI:10.1016/S0020-1693(96)05411-4

upstream raw materials:

silver tetrafluoroborate

bis(triphenylphosphine)copper(I) chloride

Perinaphthenon