(H(C₄H₃SCOHC₆H₅)C₆H₄OCH₃)Mn(CO)3

Base Information

Chemical Name:(H(C₄H₃SCOHC₆H₅)C₆H₄OCH₃)Mn(CO)3
CAS No.:1219716-67-2
Molecular Formula:C₂₁H₁₇MnO₅S
Molecular Weight:436.367
Hs Code.:

(H(C<sub>4</sub>H<sub>3</sub>SCOHC<sub>6</sub>H<sub>5</sub>)C<sub>6</sub>H<sub>4</sub>OCH<sub>3</sub>)Mn(CO)3

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Chemical Property of (H(C₄H₃SCOHC₆H₅)C₆H₄OCH₃)Mn(CO)3

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Technology Process of (H(C₄H₃SCOHC₆H₅)C₆H₄OCH₃)Mn(CO)3

There total 1 articles about (H(C₄H₃SCOHC₆H₅)C₆H₄OCH₃)Mn(CO)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 356786-27-1
(η5-1-C(O)(2-thienyl)-4-OMe-cyclohexadienyl)tricarbonylmanganese

: 100-59-4
phenylmagnesium chloride

: 7732-18-5
water

: 1219716-67-2
(H(C₄H₃SCOHC₆H₅)C₆H₄OCH₃)Mn(CO)3

Guidance literature:: In tetrahydrofuran; (inert atm.) to a soln. of complex in THF was added C6H5MgCl (2 equiv) at 0°C, the soln. was stirred at 0°C for 20 min, water was added; the aq. phase was extd. with diethyl ether, the organic phase was washedwith water and satd. soln. of NaCl, dried over MgSO4, concd. in vac., f lash chromy. on silica gel; elem. anal.;
DOI:10.1021/om100062m

Reference yield: 39.0%

: 1219716-67-2
(H(C₄H₃SCOHC₆H₅)C₆H₄OCH₃)Mn(CO)3

: 341-02-6
trityl tetrafluoroborate

: 1219716-70-7
((C₄H₃SCOHC₆H₅)C₆H₄OCH₃)Mn(CO)3⁽¹⁺⁾*BF₄^(1-)=((C₄H₃SCOHC₆H₅)C₆H₄OCH₃)Mn(CO)3BF₄

Guidance literature:: In dichloromethane; (inert atm.) to a soln. of complex in CH2Cl2 was added 1 equiv of C(C6H5)3BF4 in CH2Cl2, the mixt. was stirred at room temp. for 30 min; pptn. by adding of diethyl ether, filtered, washed with diethyl ether and dried in vac.; elem. anal.;
DOI:10.1021/om100062m