η5-cyclopentadienyl(dicarbonyl)(dimethylphenylphosphine)iron iodide

Base Information

• Chemical Name: η5-cyclopentadienyl(dicarbonyl)(dimethylphenylphosphine)iron iodide
• CAS No.: 32842-62-9
• Molecular Formula: C₁₅H₁₆FeO₂P*I
• Molecular Weight: 442.016
• Mol file: 32842-62-9.mol

Synonyms:

Chemical Property of η5-cyclopentadienyl(dicarbonyl)(dimethylphenylphosphine)iron iodide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of η5-cyclopentadienyl(dicarbonyl)(dimethylphenylphosphine)iron iodide

There total 2 articles about η5-cyclopentadienyl(dicarbonyl)(dimethylphenylphosphine)iron iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

dicarbonylcyclopentadienyliodoiron(II) (12078-28-3,38979-86-1) + Dimethyl(phenyl)phosphine (672-66-2) → η5-cyclopentadienyl(carbonyl)(iodo)(dimethylphenylphosphine)iron (31871-72-4) + η5-cyclopentadienyl(dicarbonyl)(dimethylphenylphosphine)iron iodide (32842-62-9)

Guidance literature:

cyclopentadienyl iron(II) dicarbonyl dimer; In benzene; mixt. of Fe-compds. in benzene is refluxed, ligand is added, react. time is 10 min (N2); monitored by IR and TLC, soln. is cooled, filtered through cellulose column, concd., and chromd. on silica gel/benzene eluent (iodo-compd.), elution with CH2Cl2 from cellulose column gives salt, crystd. from CH2Cl2/hexane, elem. anal.;

DOI:10.1016/0022-328X(87)80253-X

Reference yield: 63.0%

dicarbonylcyclopentadienyliodoiron(II) (12078-28-3,38979-86-1) + Dimethyl(phenyl)phosphine (672-66-2) → η5-cyclopentadienyl(dicarbonyl)(dimethylphenylphosphine)iron iodide (32842-62-9)

Guidance literature:

In toluene; phosphine and Fe compd. (1:1.2 molar ratio) stirred at room temp. overnight; septd., washed (toluene), recrystd. (DCM/Et2O);

DOI:10.1016/j.ica.2011.10.048

upstream raw materials:

dicarbonylcyclopentadienyliodoiron(II)

Dimethyl(phenyl)phosphine