η5-cyclopentadienyl(carbonyl)(iodo)(dimethylphenylphosphine)iron

Base Information

• Chemical Name: η5-cyclopentadienyl(carbonyl)(iodo)(dimethylphenylphosphine)iron
• CAS No.: 31871-72-4
• Molecular Formula: C₁₄H₁₆FeIOP
• Molecular Weight: 414.006
• Mol file: 31871-72-4.mol

Synonyms:η5-cyclopentadienyl(carbonyl)(iodo)(dimethylphenylphosphine)iron

Chemical Property of η5-cyclopentadienyl(carbonyl)(iodo)(dimethylphenylphosphine)iron

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of η5-cyclopentadienyl(carbonyl)(iodo)(dimethylphenylphosphine)iron

There total 3 articles about η5-cyclopentadienyl(carbonyl)(iodo)(dimethylphenylphosphine)iron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

dicarbonylcyclopentadienyliodoiron(II) (12078-28-3,38979-86-1) + Dimethyl(phenyl)phosphine (672-66-2) → η5-cyclopentadienyl(carbonyl)(iodo)(dimethylphenylphosphine)iron (31871-72-4) + η5-cyclopentadienyl(dicarbonyl)(dimethylphenylphosphine)iron iodide (32842-62-9)

Guidance literature:

cyclopentadienyl iron(II) dicarbonyl dimer; In benzene; mixt. of Fe-compds. in benzene is refluxed, ligand is added, react. time is 10 min (N2); monitored by IR and TLC, soln. is cooled, filtered through cellulose column, concd., and chromd. on silica gel/benzene eluent (iodo-compd.), elution with CH2Cl2 from cellulose column gives salt, crystd. from CH2Cl2/hexane, elem. anal.;

DOI:10.1016/0022-328X(87)80253-X

Reference yield:

dicarbonylcyclopentadienyliodoiron(II) (12078-28-3,38979-86-1) + Dimethyl(phenyl)phosphine (672-66-2) → η5-cyclopentadienyl(carbonyl)(iodo)(dimethylphenylphosphine)iron (31871-72-4)

Guidance literature:

In tetrahydrofuran; at 85 ℃; Inert atmosphere; Glovebox;

DOI:10.1016/j.poly.2018.09.062

Reference yield:

(η5-C5H5)Fe(CO)(PMe2Ph)H + methyl iodide (74-88-4) → η5-cyclopentadienyl(carbonyl)(iodo)(dimethylphenylphosphine)iron (31871-72-4)

Guidance literature:

With Ph₃C-CPH₃; In benzene; N2-atmosphere; treatment of mixt. of Fe-complex and MeI with trityl dimer; not isolated, detd. by IR and NMR spectroscopy;

DOI:10.1016/S0022-328X(96)06623-5

upstream raw materials:

methyl iodide

dicarbonylcyclopentadienyliodoiron(II)

Dimethyl(phenyl)phosphine

Downstream raw materials:

ferrocene

(η5-1-(CO2C2H5)-2,4-dimethylcyclopentadienyl)dicarbonylruthenium(II) iodide

(η5-1-(CO2C2H5)-2,4-dimethylcyclopentadienyl)(η5-cyclopentadienyl)ruthenium(II)

[(η5-C5H2(Me)2(COOEt))Ru(CO)(PMe2Ph)I]